SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	AMMONIUM CERIC NITRATE 0.05 N
Catalogue No. :	AL0337	Product form :	Mixture
CAS Number :	16774-21-3	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	38220090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		16774-21-3
3.2. Mixture
Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
WATER AR	(CAS-No.) 7732-18-5 (EC-No.) 231-791-2	89 - 90	Not classified
NITRIC ACID	(CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1	10 - 10.5	Ox. Liq. 2, H272 Skin Corr. 1A, H314
AMMONIUM CERIC NITRATE AR/ACS	(CAS-No.) 16774-21-3	2.5 - 3	Ox. Sol. 2, H272 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335
Full text of H-statements: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Avoid contact with skin, eyes and clothing.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean contaminated surfaces with an excess of water.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
NITRIC ACID (7697-37-2) Germany TRGS 900 Local name Salpetersäure Germany TRGS 900 Occupational exposure limit value (mg/m³) 2.6 mg/m³ Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm Germany TRGS 900 Remark EU,13,16 Portugal Local name Ácido nítrico Portugal OEL TWA (ppm) 2 ppm Portugal OEL STEL (ppm) 4 ppm Spain Local name Ácido nítrico Spain VLA-EC (mg/m³) 2.6 mg/m³ Spain VLA-EC (ppm) 1 ppm NITRIC ACID (7697-37-2) Spain Notes (2007), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados,estos valores tienen la misma validez que el resto de los valores adoptados por el país.) United Kingdom Local name Nitric acid United Kingdom WEL STEL (mg/m³) 2.6 mg/m³ United Kingdom WEL STEL (ppm) 1 ppm USA - ACGIH Local name Nitric acid USA - ACGIH ACGIH TWA (ppm) 2 ppm USA - ACGIH ACGIH STEL (ppm) 4 ppm USA - ACGIH Remark (ACGIH) URT & eye irr; dental erosion USA - OSHA Local name Nitric acid USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ USA - OSHA OSHA PEL (TWA) (ppm) 2 ppm
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	548.22 g/mol
Colour :	Yellowish orange liquid.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-41.6 °C
Freezing point :	No data available
Boiling point :	83 °C
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	No data available
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	NITRIC ACID (7697-37-2) Persistence and degradability Not established.
12.3 Bioaccumulative potential
Bioaccumulative potential :	NITRIC ACID (7697-37-2) Bioaccumulative potential Not established.
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info :	No additional information available

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	Not applicable
UN-No. (IMDG) :	Not applicable
UN-No. (IATA) :	Not applicable
UN-No. (ADN) :	Not applicable
UN-No. (RID) :	Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	Not applicable
Proper Shipping Name (IMDG) :	Not applicable
Proper Shipping Name (IATA) :	Not applicable
Proper Shipping Name (ADN) :	Not applicable
Proper Shipping Name (RID) :	Not applicable
Transport document description (ADR) :	Not applicable
Transport document description (IMDG) :	Not applicable
Transport document description (IATA) :	Not applicable
Transport document description (ADN) :	Not applicable
Transport document description (RID) :	Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	Not applicable
IMDG
Transport hazard class(es) :	Not applicable
IATA
Transport hazard class(es) :	Not applicable
ADN
Transport hazard class(es) :	Not applicable
RID
Transport hazard class(es) :	Not applicable
14.4. Packing group
Packing group (ADR) :	Not applicable
Packing group (IMDG) :	Not applicable
Packing group (IATA) :	Not applicable
Packing group (ADN) :	Not applicable
Packing group (RID) :	Not applicable
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Not applicable
- Transport by sea
Not applicable
- Air transport
Not applicable
- Inland waterway transport
Not applicable
- Rail transport
Not applicable
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Ox. Liq. 2 Oxidising Liquids, Category 2 Ox. Sol. 2 Oxidising Solids, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.