SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	BARIUM PERCHLORATE 0.005 MOL/Liter (0.005M) alcoholic solution
Catalogue No. :	AL0567	Product form :	Mixture
CAS Number :	13465-95-7	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, Category 2 H272 Acute toxicity (oral), Category 4 H302 Acute toxicity (inhal.), Category 4 H332 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R8 Xn; R20/22 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS03 GHS07
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H272 - May intensify fire; oxidiser H302+H332 - Harmful if swallowed or if inhaled
Precautionary statements (CLP) :	P220 - Keep/Store away from clothing, combustible materials
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		BARIUM PEROXIDE Extra Pure
CAS No. :		13465-95-7
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact :	Gently wash with plenty of soap and water.
First-aid measures after eye contact :	Rinse immediately with plenty of water.
First-aid measures after ingestion :	Rinse mouth.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	May cause fire or explosion; strong oxidiser.
Explosion hazard :	Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Hazardous decomposition products in case of fire : Thermal decomposition generates :
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Hazardous waste due to potential risk of explosion.
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours. Take precautionary measures against static discharge. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Colour
Colour :	Off white powder.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	450 °C
Freezing point :	No data available
Boiling point :	800 °C
Flash point :	21 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	4.96 g/cm3
Solubility :	Water: Insoluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	May cause fire or explosion; strong oxidiser.
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
May cause fire or explosion; strong oxidiser.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Heat. Sparks. Open flame.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Inhalation: Harmful if inhaled.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1449
UN-No. (IMDG) :	1449
UN-No. (IATA) :	1449
UN-No. (ADN) :	1449
UN-No. (RID) :	1449
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	BARIUM PEROXIDE
Proper Shipping Name (IMDG) :	BARIUM PEROXIDE
Proper Shipping Name (IATA) :	BARIUM PEROXIDE
Proper Shipping Name (ADN) :	BARIUM PEROXIDE
Proper Shipping Name (RID) :	BARIUM PEROXIDE
Transport document description (ADR) :	UN 1449, BARIUM PEROXIDE, 5.1 (6.1), II
Transport document description (IMDG) :	UN 1449, BARIUM PEROXIDE, 5.1 (6.1), II
Transport document description (IATA) :	UN 1449, BARIUM PEROXIDE, 5.1 (6.1), II
Transport document description (ADN) :	UN 1449, BARIUM PEROXIDE, 5.1 (6.1), II
Transport document description (RID) :	UN 1449, BARIUM PEROXIDE, 5.1 (6.1), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
IMDG
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
IATA
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
ADN
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
RID
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OT2 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E2 Packing instructions (ADR) : P002, IBC06 Mixed packing provisions (ADR) : MP2 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Tank special provisions (ADR) : TU3 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24, CV28 Hazard identification number (Kemler No.) : 56 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1Y
- Transport by sea
Limited quantities (IMDG) : 1 kg Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC06 IBC special provisions (IMDG) : B2 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-G EmS-No. (Spillage) : S-Q Stowage category (IMDG) : C Stowage and handling (IMDG) : H1 Segregation (IMDG) : SG16, SG35, SG59, SG26, SG36 MFAG-No : 141
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y543 PCA limited quantity max net quantity (IATA) : 1kg PCA packing instructions (IATA) : 558 PCA max net quantity (IATA) : 5kg CAO packing instructions (IATA) : 562 CAO max net quantity (IATA) : 25kg ERG code (IATA) : 5P
- Inland waterway transport
Classification code (ADN) : OT2 Special provisions (ADN) : 802 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : OT2 Limited quantities (RID) : 1kg Excepted quantities (RID) : E2 Packing instructions (RID) : P002, IBC06 Mixed packing provisions (RID) : MP2 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Special provisions for RID tanks (RID) : TU3 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage – Loading and unloading (RID) : CW24, CW28 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 56
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Barium peroxide is not on the REACH Candidate List Barium peroxide is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 307) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information
Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Ox. Sol. 2 Oxidising Solids, Category 2 H272 May intensify fire; oxidiser H302 Harmful if swallowed H332 Harmful if inhaled R20/22 Harmful by inhalation and if swallowed R8 Contact with combustible material may cause fire O Oxidising Xn Harmful