POTASSIUM DICHROMATE 0.02 M/L SOLUTION FOR DETERMINATION OF COD

POTASSIUM DICHROMATE 0.02 M/L SOLUTION FOR DETERMINATION OF COD

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : POTASSIUM DICHROMATE 0.02M/L SOLUTION
Catalogue No. : AL3686 Product form : Mixture
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 38220090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
Muta.Cat.2; R46
Repr.Cat.2; R60
Repr.Cat.2; R61
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water (CAS No) 7732-18- 5 (EC no) 231-791-2 >= 99 Not classified Not classified
Potassium dichromate substance listed as REACH Candidate substance listed in REACH Annex XIV (CAS No) 7778-50- 9 (EC no) 231-906-6 (EC index no) 024- 002-00-6 0.01 - 1 Carc.Cat.1; R45 Muta.Cat.1; R46 Repr.Cat.1; R60 Repr.Cat.1; R61 O; R8 T+; R26 T; R25 T; R48/23 Xn; R21 R42 C; R34 R43 N; R50/53 Acute Tox. 2 (Inhalation), H330 Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Aquatic Acute 1, H400
Full text of R- and H-phrases: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical
advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : May cause genetic defects. May cause cancer. May damage the unborn child. May
damage fertility.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Orange.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 1 g/cm3
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Irritation : Not classified
Corrosivity : Not classified
Sensitisation : Not classified
Repeated dose toxicity : Not classified
Carcinogenicity : May cause cancer.
Mutagenicity : May cause heritable genetic damage.
Toxicity for reproduction : May impair fertility. May caus
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :
Germ cell mutagenicity :
Carcinogenicity :

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
Component
Potassium dichromate (7778-50-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex
XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : Not applicable
UN-No. (IMDG) : Not applicable
UN-No. (IATA) : Not applicable
UN-No. (ADN) : Not applicable
UN-No. (RID) : Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : Not applicable
Transport document description (IMDG) : Not applicable
Transport document description (IATA) : Not applicable
Transport document description (ADN) : Not applicable
Transport document description (RID) : Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : Not applicable
IMDG
Transport hazard class(es) : Not applicable
IATA
Transport hazard class(es) : Not applicable
ADN
Transport hazard class(es) : Not applicable
RID
Transport hazard class(es) : Not applicable
14.4. Packing group
Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions
Contains substance on the candidate list in concentration ≥ 0.1% or with a lower specific limit: Potassium dichromate (EC 231-906-
6, CAS 7778-50-9)
Contains REACH Annex XIV substances:
Substance name Authorisation number Sunset date REACH authorization
exemptions
Potassium dichromate (EC
231-906-6, CAS 7778-50-9)
21/09/2017
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
H301 Toxic if swallowed
H312 Harmful in contact with skin
H330 Fatal if inhaled
H400 Very toxic to aquatic life
R21 Harmful in contact with skin
R25 Toxic if swallowed
R26 Very toxic by inhalation
R34 Causes burns
R42 May cause sensitization by inhalation
R43 May cause sensitisation by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R60 May impair fertility
R61 May cause harm to the unborn child
R8 Contact with combustible material may cause fire
C Corrosive
N Dangerous for the environment
O Oxidising
T Toxic
T+ Very toxic
Xn Harmful