SULPHURIC ACID 5M (10N) STANDARDIZED SOLUTION traceable to NIST

SULPHURIC ACID 5M (10N) STANDARDIZED SOLUTION traceable to NIST

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : SULPHURIC ACID 5M (10N)
Catalogue No. : AL4422 Product form : Mixture
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 38220090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R35
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water (CAS-No.) 7732-18- 5 (EC-No.) 231-791-2 50 - 75 Not classified Not classified
Sulphuric acid (CAS-No.) 7664-93- 9 (EC-No.) 231-639-5 (EC Index-No.) 016- 020-00-8 25 - 50 C; R35 Skin Corr. 1A, H314 Eye Dam. 1, H318
Full text of R- and H-statements: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Equip cleanup crew with proper protection
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean contaminated surfaces with an excess of water.
6.4 Reference to other sections
Reference : See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contac
Hygiene measures : Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep
container closed when not in use.
Incompatible products : Strong bases. Strong acids.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : characteristic.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable.
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Irritation : Not classified
Corrosivity : Causes severe burns.
Sensitisation : Not classified
Repeated dose toxicity : Not classified
Carcinogenicity : Not classified
Mutagenicity : Not classified
Toxicity for reproduction : Not classified
Potential adverse human health effects
and symptoms
: Based on available data, the classific
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :
Germ cell mutagenicity :
Carcinogenicity : Not classifie
Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : SULPHURIC ACID 5M (10N) STANDARDIZED SOLUTION traceable to NIST Persistence and degradability Not established.
12.3 Bioaccumulative potential
Bioaccumulative potential : SULPHURIC ACID 5M (10N) STANDARDIZED SOLUTION traceable to NIST Bioaccumulative potential Not established.
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2796
UN-No. (IMDG) : 2796
UN-No. (IATA) : 2796
UN-No. (ADN) : 2796
UN-No. (RID) : 2796
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SULPHURIC ACID
Proper Shipping Name (IMDG) : SULPHURIC ACID
Proper Shipping Name (IATA) : SULPHURIC ACID
Proper Shipping Name (ADN) : SULPHURIC ACID
Proper Shipping Name (RID) : SULPHURIC ACID
Transport document description (ADR) : UN 2796, SULPHURIC ACID, 8, II
Transport document description (IMDG) : UN 2796, SULPHURIC ACID, 8, II
Transport document description (IATA) : UN 2796, SULPHURIC ACID, 8, II
Transport document description (ADN) : UN 2796, SULPHURIC ACID, 8, II
Transport document description (RID) : UN 2796, SULPHURIC ACID, 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8
Danger labels : 8
IMDG
Transport hazard class(es) : 8
Danger labels : 8
IATA
Transport hazard class(es) : 8
Danger labels : 8
ADN
Transport hazard class(es) : 8
Danger labels : 8
RID
Transport hazard class(es) : 8
Danger labels : 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C1
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T8
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2R
- Transport by sea
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
IBC special provisions (IMDG) : B20
Tank instructions (IMDG) : T8
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Properties and observations (IMDG) : Colourless liquid, mixture not exceeding 1.405 relative density. Highly corrosive to
most metals. Causes burns to skin, eyes and mucous membranes.
MFAG-No : 157
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C1
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C1
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T8
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, Highly hazardous to water (Classification according to
AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : Sulphuric acid is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: None of the components are listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No chemical safety assessment has been carried out

SECTION 16: Other Information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF
THE COUNCIL of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, am