BENZOYL CHLORIDE Extra Pure |
| Synonyms : Benzenecarbonyl chloride; Benzoic acid chloride; alpha-Chloroenzaldehyde |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | BENZOYL CHLORIDE | ||
| Catalogue No. : | AL0638 | Product form : | Substance |
| CAS Number : | 98-88-4 | EC Number : | 202-710-8 |
| Grade : | EC Index Number : | 607-012-00-0 | |
| Chemical Formula : | HSN Code : | 29163200 | |
| Synonyms : | Benzenecarbonyl chloride; Benzoic acid chloride; alpha-Chloroenzaldehyde | ||
| Chemical Structure : |
|
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Skin corrosion/irritation, Category 1B H314 Serious eye damage/eye irritation, Category 1 H318 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Sensitisation Skin, category 1 H317 Full text of classification categories and H statements : see section 16 |
|
| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R20/21/22 C; R34 R43 Full text of R-phrases: see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS07
|
| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction |
| Precautionary statements (CLP) : | P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician |
2.3 Other hazards |
|
| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Name : | BENZOYL CHLORIDE Extra Pure | ||
| CAS No. : | 98-88-4 | ||
| EC Index No. : | 607-012-00-0 | ||
| EC No. : | 202-710-8 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Not applicable | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | Assure fresh air breathing. Allow the victim to rest. |
| First-aid measures after skin contact : | Wash with plenty of soap and water. Get medical advice/attention. Wash contaminated clothing before reuse. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
| Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
6.2 Environmental precautions |
|
| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Precautions for safe handling : | Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Technical measures : | Comply with applicable regulations. |
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear appropriate mask |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Liquid Colour |
| Colour : | Clear Colorless. |
| Odour : | penetrating odor. |
| Odour threshold : | No data available |
| pH value : | 2 at 1 g/l |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -1 °C |
| Freezing point : | No data available |
| Boiling point : | 198 °C |
| Flash point : | 72 °C |
| Auto-ignition temperature : | 6000 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 1 mm Hg at 320C |
| Relative vapour density at 20°C : | 4.88 |
| Density : | 1.211 g/cm3 |
| Solubility : | Water: Decomposed by water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.012 - 0.049 vol % |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
|
| Stable under normal conditions of use. | |
10.3 Possibility of hazardous reactions |
|
| No additional information available | |
10.4 Conditions to avoid |
|
| Direct sunlight. Overheating. Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled. Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. pH: 2 at 1 g/l |
| Serious eye damage/irritation : | Causes serious eye damage. pH: 2 at 1 g/l |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| No additional information available | |
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 1736 |
| UN-No. (IMDG) : | 1736 |
| UN-No. (IATA) : | 1736 |
| UN-No. (ADN) : | 1736 |
| UN-No. (RID) : | 1736 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | BENZOYL CHLORIDE |
| Proper Shipping Name (IMDG) : | BENZOYL CHLORIDE |
| Proper Shipping Name (IATA) : | BENZOYL CHLORIDE |
| Proper Shipping Name (ADN) : | BENZOYL CHLORIDE |
| Proper Shipping Name (RID) : | BENZOYL CHLORIDE |
| Transport document description (ADR) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (IMDG) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (IATA) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (ADN) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (RID) : | UN 1736, BENZOYL CHLORIDE, 8, II |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
|
| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
14.4. Packing group |
|
| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
|
| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : C3 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 4W |
|
| - Transport by sea | |
|
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : C Stowage and handling (IMDG) : SW2 MFAG-No : 137 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8W |
|
| - Inland waterway transport | |
|
Classification code (ADN) : C3 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
|
| - Rail transport | |
|
Classification code (RID) : C3 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T8 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions BENZOYL CHLORIDE Extra Pure is not on the REACH Candidate List BENZOYL CHLORIDE Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 2118) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
|||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
|||||||||||||||||||