BENZOYL CHLORIDE AR |
| Synonyms : Benzenecarbonyl chloride; Benzoic acid chloride; alpha-Chloroenzaldehyde |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | BENZOYL CHLORIDE AR | ||
| Catalogue No. : | AL0639 | Product form : | Substance |
| CAS Number : | 98-88-4 | EC Number : | 202-710-8 |
| Grade : | EC Index Number : | 607-012-00-0 | |
| Chemical Formula : | HSN Code : | 29163200 | |
| Synonyms : | Benzenecarbonyl chloride; Benzoic acid chloride; alpha-Chloroenzaldehyde | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Skin corrosion/irritation, Category 1B H314 Serious eye damage/eye irritation, Category 1 H318 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Skin sensitisation, Category 1 H317 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R20/21/22 C; R34 R43 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS07
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. |
| Precautionary statements (CLP) : | P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | BENZOYL CHLORIDE AR | ||
| CAS No. : | 98-88-4 | ||
| EC Index No. : | 607-012-00-0 | ||
| EC No. : | 202-710-8 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Comply with applicable regulations. |
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear appropriate mask |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid Colour |
| Colour : | Clear Colorless. |
| Odour : | penetrating odor. |
| Odour threshold : | No data available |
| pH value : | 2 at 1 g/l |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -1 °C |
| Freezing point : | No data available |
| Boiling point : | 198 °C |
| Flash point : | 72 °C |
| Auto-ignition temperature : | 6000 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 1 mm Hg at 320C |
| Relative vapour density at 20°C : | 4.88 |
| Density : | 1.211 g/cm3 |
| Solubility : | Water: Decomposed by water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.012 - 0.049 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Overheating. Direct sunlight. Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled. Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. pH: 2 at 1 g/l |
| Serious eye damage/irritation : | Causes serious eye damage. pH: 2 at 1 g/l |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1736 |
| UN-No. (IMDG) : | 1736 |
| UN-No. (IATA) : | 1736 |
| UN-No. (ADN) : | 1736 |
| UN-No. (RID) : | 1736 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | BENZOYL CHLORIDE |
| Proper Shipping Name (IMDG) : | BENZOYL CHLORIDE |
| Proper Shipping Name (IATA) : | BENZOYL CHLORIDE |
| Proper Shipping Name (ADN) : | BENZOYL CHLORIDE |
| Proper Shipping Name (RID) : | BENZOYL CHLORIDE |
| Transport document description (ADR) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (IMDG) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (IATA) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (ADN) : | UN 1736, BENZOYL CHLORIDE, 8, II |
| Transport document description (RID) : | UN 1736, BENZOYL CHLORIDE, 8, II |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
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| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : C3 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 4W |
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| - Transport by sea | |
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Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : C Stowage and handling (IMDG) : SW2 MFAG-No : 137 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8W |
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| - Inland waterway transport | |
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Classification code (ADN) : C3 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : C3 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T8 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions BENZOYL CHLORIDE AR is not on the REACH Candidate List BENZOYL CHLORIDE AR is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 2118) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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