ACETYL BROMIDE For Synthesis |
Synonyms : Ethanoyl bromide |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
---|---|---|---|
1.1 Product identifier |
|||
Chemical Name : | Acetyl bromide | ||
Catalogue No. : | AL0067 | Product form : | Substance |
CAS Number : | 506-96-7 | EC Number : | 208-061-7 |
Grade : | EC Index Number : | 208-061-7 | |
Chemical Formula : | HSN Code : | 29159090 | |
Synonyms : | Ethanoyl Bromide | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
|
---|---|
2.1 Classification of the substance or mixture |
|
Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Skin corrosion/irritation, Category 1B H314 Full text of classification categories and H statements : see section 16 |
|
Classification according to Directive 67/548/EEC or 1999/45/EC | |
C; R34 R14 Full text of R-phrases: see section 16 |
|
Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
|
Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS05 |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H314 - Causes severe skin burns and eye damage |
Precautionary statements (CLP) : | P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor EUH phrases : EUH014 - Reacts violently with water |
2.3 Other hazards |
|
Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
---|---|---|---|
3.1. Substance |
|||
Name : | ACETYL BROMIDE FOR SYNTHESIS | ||
CAS No. : | 506-96-7 | ||
EC Index No. : | 208-061-7 | ||
EC No. : | 208-061-7 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
Not applicable |
SECTION 4: First aid measures |
|
---|---|
4.1 Description of first aid measures |
|
First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. |
First-aid measures after skin contact : | Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. |
First-aid measures after ingestion : | Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. |
4.2 Most important symptoms and effects, both acute and delayed |
|
Symptoms relating to use : | Symptoms/injuries : Causes severe skin burns and eye damage. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
---|---|
5.1 Extinguishing media |
|
Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
|
Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
|
---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
Protective equipment | Use personal protective equipment as required |
Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. |
6.4 Reference to other sections |
|
Reference : | No additional information available |
SECTION 7: Handling and storage |
|
---|---|
7.1 Precautions for safe handling |
|
Precautions for safe handling : | Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. |
Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
|
Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
No additional information available |
SECTION 8: Exposure controls/personal protection |
|
---|---|
8.1 Control parameters |
|
No additional information available | |
8.2 Exposure controls |
|
Hand protection : | Protective gloves |
Eye protection : | Chemical goggles or face shield |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
---|---|
9.1 Information on basic physical and chemical properties |
|
Physical state : | Liquid |
Colour : | Clear Colorless. |
Odour : | pungent odour. |
Odour threshold : | No data available |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | -96 °C |
Freezing point : | No data available |
Boiling point : | 75 - 77 °C |
Flash point : | 110 °C |
Auto-ignition temperature : | No data available |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | No data available |
Vapour pressure : | No data available |
Relative vapour density at 20°C : | 4.24 |
Density : | 1.663 g/cm3 |
Solubility : | Water: Soluble in water |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | No data available |
9.2 Other information |
|
No additional information available |
SECTION 10: Stability and reactivity |
|
---|---|
10.1 Reactivity |
|
Thermal decomposition generates : Corrosive vapours. Reacts violently with water. | |
10.2 Chemical stability |
|
Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
Highly reactive material. Reacts violently with water. | |
10.4 Conditions to avoid |
|
Moisture. | |
10.5 Incompatible materials |
|
No additional information available | |
10.6 Hazardous decomposition products |
|
Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
|
---|---|
11.1 Information on toxicological effects |
|
Acute toxicity : | Not classified |
Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Not classified |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | Not classified |
Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
|
---|---|
12.1 Toxicity |
|
Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
No additional information available | |
12.6 Other adverse effects |
|
Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
---|---|
13.1 Waste treatment methods |
|
Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
Additional information : | Do not allow water (or moist air) contact with this material. |
SECTION 14: Transport information |
|
---|---|
In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
UN-No. (ADR) : | 1716 |
UN-No. (IMDG) : | 1716 |
UN-No. (IATA) : | 1716 |
UN-No. (ADN) : | 1716 |
UN-No. (RID) : | 1716 |
14.2. UN proper shipping name |
|
Proper Shipping Name (ADR) : | ACETYL BROMIDE |
Proper Shipping Name (IMDG) : | ACETYL BROMIDE |
Proper Shipping Name (IATA) : | ACETYL BROMIDE |
Proper Shipping Name (ADN) : | ACETYL BROMIDE |
Proper Shipping Name (RID) : | ACETYL BROMIDE |
Transport document description (ADR) : | UN 1716, ACETYL BROMIDE, 8, II |
Transport document description (IMDG) : | UN 1716, ACETYL BROMIDE, 8, II |
Transport document description (IATA) : | UN 1716, ACETYL BROMIDE, 8, II |
Transport document description (ADN) : | UN 1716, ACETYL BROMIDE, 8, II |
Transport document description (RID) : | UN 1716, ACETYL BROMIDE, 8, II |
14.3. Transport hazard class(es) |
|
ADR | |
Transport hazard class(es) : | 8 |
Danger labels : | 8 |
IMDG | |
Transport hazard class(es) : | 8 |
Danger labels : | 8 |
IATA | |
Transport hazard class(es) : | 8 |
Danger labels : | 8 |
ADN | |
Transport hazard class(es) : | 8 |
Danger labels : | 8 |
RID | |
Transport hazard class(es) : | 8 |
Danger labels : | 8 |
14.4. Packing group |
|
Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
|
Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
|
- Overland transport | |
Classification code (ADR) : C3 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 4W |
|
- Transport by sea | |
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : C Stowage and handling (IMDG) : SW2 MFAG-No : 156 |
|
- Air transport | |
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8L |
|
- Inland waterway transport | |
Classification code (ADN) : C3 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
|
- Rail transport | |
Classification code (RID) : C3 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T8 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
Not applicable |
SECTION 15: Regulatory information |
---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions Acetyl bromide is not on the REACH Candidate List Acetyl bromide is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
---|