ACETYL BROMIDE For Synthesis

ACETYL BROMIDE For Synthesis

Synonyms : Ethanoyl bromide

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : Acetyl bromide
Catalogue No. : AL0067 Product form : Substance
CAS Number : 506-96-7 EC Number : 208-061-7
Grade : EC Index Number : 208-061-7
Chemical Formula : HSN Code : 29159090
Synonyms : Ethanoyl Bromide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation,
Category 1B
H314
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R34
R14
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS05GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protection, face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a doctor
EUH phrases : EUH014 - Reacts violently with water
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : ACETYL BROMIDE FOR SYNTHESIS
CAS No. : 506-96-7
EC Index No. : 208-061-7
EC No. : 208-061-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or
doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Causes severe skin burns and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Colour : Clear Colorless.
Odour : pungent odour.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -96 °C
Freezing point : No data available
Boiling point : 75 - 77 °C
Flash point : 110 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : 4.24
Density : 1.663 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours. Reacts violently with water.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Highly reactive material. Reacts violently with water.
10.4 Conditions to avoid
Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Additional information : Do not allow water (or moist air) contact with this material.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1716
UN-No. (IMDG) : 1716
UN-No. (IATA) : 1716
UN-No. (ADN) : 1716
UN-No. (RID) : 1716
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ACETYL BROMIDE
Proper Shipping Name (IMDG) : ACETYL BROMIDE
Proper Shipping Name (IATA) : ACETYL BROMIDE
Proper Shipping Name (ADN) : ACETYL BROMIDE
Proper Shipping Name (RID) : ACETYL BROMIDE
Transport document description (ADR) : UN 1716, ACETYL BROMIDE, 8, II
Transport document description (IMDG) : UN 1716, ACETYL BROMIDE, 8, II
Transport document description (IATA) : UN 1716, ACETYL BROMIDE, 8, II
Transport document description (ADN) : UN 1716, ACETYL BROMIDE, 8, II
Transport document description (RID) : UN 1716, ACETYL BROMIDE, 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8
Danger labels : 8
IMDG
Transport hazard class(es) : 8
Danger labels : 8
IATA
Transport hazard class(es) : 8
Danger labels : 8
ADN
Transport hazard class(es) : 8
Danger labels : 8
RID
Transport hazard class(es) : 8
Danger labels : 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C3
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T8
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 4W
- Transport by sea
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
IBC special provisions (IMDG) : B20
Tank instructions (IMDG) : T8
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : C
Stowage and handling (IMDG) : SW2
MFAG-No : 156
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C3
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C3
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T8
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Acetyl bromide is not on the REACH Candidate List
Acetyl bromide is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information