SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	ETHYL CHLOROFORMATE (for synthesis)
Catalogue No. :	AL2065	Product form :	Substance
CAS Number :	541-41-3	EC Number :	208-778-5
Grade :		EC Index Number :	607-020-00-4
Chemical Formula :	C3H5ClO2	HSN Code :	29153990
Synonyms :	Ethyl chlorocarbonate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Acute toxicity (oral), Category 4 H302 Acute toxicity (inhal.), Category 2 H330 Skin corrosion/irritation, Category 1B H314 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11 T+; R26 Xn; R22 C; R34 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS06
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour. H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H330 - Fatal if inhaled.
Precautionary statements (CLP) :	P210 - Keep away from heat, open flames, sparks. No smoking. P260 - Do not breathe vapours, spray, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P284 - Wear respiratory protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor EUH-statements : EUH071 - Corrosive to the respiratory tract.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		ETHYL CHLOROFORMATE FOR SYNTHESIS
CAS No. :		541-41-3
EC Index No. :		607-020-00-4
EC No. :		208-778-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. Wash with plenty of water/….
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : Fatal if inhaled. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	Keep away from sources of ignition - No smoking. Use only non-sparking tools. Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	108.53 g/mol
Colour :	Clear Colorless.
Odour :	No data available
Odour threshold :	No data available
pH value :	7
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-81 °C
Freezing point :	No data available
Boiling point :	93 °C
Flash point :	10 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	Highly flammable liquid and vapour.
Vapour pressure :	54 hPa at 20 °C
Relative vapour density at 20°C :	3.75
Density :	1.135 g/cm3
Solubility :	Water: Insoluble
Log Pow :	0.3
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.037 - 0.126 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Inhalation: Fatal if inhaled.
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 7
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 7
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified Additional information : Corrosive to the respiratory tract.
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	ETHYL CHLOROFORMATE FOR SYNTHESIS (541-41-3) Log Pow 0.3
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1182
UN-No. (IMDG) :	1182
UN-No. (IATA) :	1182
UN-No. (ADN) :	1182
UN-No. (RID) :	1182
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ETHYL CHLOROFORMATE
Proper Shipping Name (IMDG) :	ETHYL CHLOROFORMATE
Proper Shipping Name (IATA) :	ETHYL CHLOROFORMATE
Proper Shipping Name (ADN) :	ETHYL CHLOROFORMATE
Proper Shipping Name (RID) :	ETHYL CHLOROFORMATE
Transport document description (ADR) :	UN 1182, ETHYL CHLOROFORMATE, 6.1 (3, 8), I
Transport document description (IMDG) :	UN 1182, ETHYL CHLOROFORMATE, 6.1 (3, 8), I
Transport document description (IATA) :	UN 1182, ETHYL CHLOROFORMATE, 6.1 (3, 8), I
Transport document description (ADN) :	UN 1182, ETHYL CHLOROFORMATE, 6.1 (3, 8), I
Transport document description (RID) :	UN 1182, ETHYL CHLOROFORMATE, 6.1 (3, 8), I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
IMDG
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
IATA
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
ADN
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
RID
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TFC Special provisions (ADR) : 354 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P602 Mixed packing provisions (ADR) : MP8, MP17 Portable tank and bulk container instructions (ADR) : T20 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE19, TE21 Vehicle for tank carriage : FL Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV1, CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S14 Hazard identification number (Kemler No.) : 663 Orange plates : Tunnel restriction code (ADR) : C/D EAC code : •3WE APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 354 Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P602 Tank instructions (IMDG) : T20 Tank special provisions (IMDG) : TP2, TP13, TP37 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2 Flash point (IMDG) : 16 °C c.c. Properties and observations (IMDG) : Colourless liquid. Flashpoint- 16 °C c.c. Reacts and decomposes with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. MFAG-No : 155
- Air transport
PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : Forbidden CAO max net quantity (IATA) : Forbidden ERG code (IATA) : 6CF
- Inland waterway transport
Classification code (ADN) : TFC Special provisions (ADN) : 354, 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TFC Special provisions (RID) : 354 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P602 Mixed packing provisions (RID) : MP8, MP17 Portable tank and bulk container instructions (RID) : T20 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Hazard identification number (RID) : 663
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions ETHYL CHLOROFORMATE FOR SYNTHESIS is not on the REACH Candidate List ETHYL CHLOROFORMATE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 7061) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Flam. Liq. 2 Flammable liquids, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H330 Fatal if inhaled. EUH071 Corrosive to the respiratory tract. R11 Highly flammable R22 Harmful if swallowed R26 Very toxic by inhalation R34 Causes burns C Corrosive F Highly flammable T+ Very toxic Xn Harmful