SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	iso-BUTYLCHLOROFORMATE 98% (for synthesis)
Catalogue No. :	AL0976	Product form :	Substance
CAS Number :	543-27-1	EC Number :	208-840-1
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29159020
Synonyms :	Chloroformic acid isobutyl ester, IBCF
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 1B H314 Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 4 H302 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R23 Xn; R22 C; R34 R10 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS06 GHS05 GHS02
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour. H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H331 - Toxic if inhaled.
Precautionary statements (CLP) :	P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		iso-BUTYL CHLOROFORMATE For Synthesis
CAS No. :		543-27-1
EC No. :		208-840-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : Toxic if inhaled. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	Fire hazard : Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Avoid contact with skin, eyes and clothing.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean contaminated surfaces with an excess of water.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions :	Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	136.58 g/mol
Colour :	Clear Colorless.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour.
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	No data available
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Inhalation: Toxic if inhaled. Oral: Harmful if swallowed.
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2742
UN-No. (IMDG) :	2742
UN-No. (IATA) :	2742
UN-No. (ADN) :	2742
UN-No. (RID) :	2742
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (IMDG) :	CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (IATA) :	CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (ADN) :	CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (RID) :	CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S.
Transport document description (ADR) :	UN 2742, CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S., 6.1 (3, 8), II
Transport document description (IMDG) :	UN 2742, CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S., 6.1 (3, 8), II
Transport document description (IATA) :	UN 2742, CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S., 6.1 (3, 8), II
Transport document description (ADN) :	UN 2742, CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S., 6.1 (3, 8), II
Transport document description (RID) :	UN 2742, CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S., 6.1 (3, 8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
IMDG
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
IATA
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
ADN
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
RID
Transport hazard class(es) :	6.1 (3, 8)
Danger labels :	6.1, 3, 8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TFC Special provisions (ADR) : 274, 561 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC01 Mixed packing provisions (ADR) : MP15 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S19 Hazard identification number (Kemler No.) : 638 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3W APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 274 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC01 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : A Stowage and handling (IMDG) : SW1, SW2, H1, H2 Segregation (IMDG) : SG5, SG8 Properties and observations (IMDG) : A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: Cyclohexyl Chloroformate: 53°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. MFAG-No : 155
- Air transport
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y640 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 653 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 660 CAO max net quantity (IATA) : 30L ERG code (IATA) : 6CF
- Inland waterway transport
Classification code (ADN) : TFC Special provisions (ADN) : 274, 561, 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TFC Special provisions (RID) : 274, 561 Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC01 Mixed packing provisions (RID) : MP15 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 638
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions iso-BUTYL CHLOROFORMATE For Synthesis is not on the REACH Candidate List iso-BUTYL CHLOROFORMATE For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1B Skin corrosion/irritation, Category 1B H226 Flammable liquid and vapour. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. R10 Flammable R22 Harmful if swallowed R23 Toxic by inhalation R34 Causes burns C Corrosive T Toxic Xn Harmful