SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	HYDROFLUORIC ACID 48% AR
Catalogue No. :	AL2465	Product form :	Mixture
CAS Number :	7664-39-3	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	28111100
Synonyms :	Hydrogen Fluride; HF
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS06 GHS05
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) :	P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P284 - Wear respiratory protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P302+P352 - IF ON SKIN: Wash with plenty of water.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		7664-39-3
3.2. Mixture
Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water	(CAS-No.) 7732-18-5 (EC-No.) 231-791-2	50 - 75	Not classified
Hydrofluoric acid - solution	(CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1	25 - 50
Acute Tox. 1 (Dermal), H310 Acute Tox. 3 (Inhalation), H331 Acute Tox. 1 (Oral), H300 Skin Corr. 1A, H314 Eye Dam. 1, H318
Full text of H-statements: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Wash with plenty of water/…. Take off immediately all contaminated clothing. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after skin contact : Fatal in contact with skin. Symptoms/effects after ingestion : Fatal if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe vapours. Avoid contact with skin and eyes.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	acrid odor.
Odour threshold :	No data available
pH value :	1
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	< -36 °C
Freezing point :	No data available
Boiling point :	108 °C
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	25 mm Hg at 20°C
Relative vapour density at 20°C :	1.97
Density :	1.15 - 1.18
Solubility :	Water: Infinitely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
No additional information available
10.5 Incompatible materials
Oxidizing agent.
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Fatal in contact with skin. Inhalation: Fatal if inhaled. Oral: Fatal if swallowed. ATE CLP (oral) 0.5 mg/kg bodyweight ATE CLP (dermal) 5 mg/kg bodyweight ATE CLP (gases) 100 ppmv/4h ATE CLP (vapours) 0.5 mg/l/4h ATE CLP (dust,mist) 0.05 mg/l/4h
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 1
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 1
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Fatal if swallowed. Fatal in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1790
UN-No. (IMDG) :	1790
UN-No. (IATA) :	1790
UN-No. (ADN) :	1790
UN-No. (RID) :	1790
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	HYDROFLUORIC ACID
Proper Shipping Name (IMDG) :	HYDROFLUORIC ACID
Proper Shipping Name (IATA) :	HYDROFLUORIC ACID
Proper Shipping Name (ADN) :	HYDROFLUORIC ACID
Proper Shipping Name (RID) :	HYDROFLUORIC ACID
Transport document description (ADR) :	UN 1790, HYDROFLUORIC ACID, 8 (6.1), II
Transport document description (IMDG) :	UN 1790, HYDROFLUORIC ACID, 8 (6.1), II
Transport document description (IATA) :	UN 1790, HYDROFLUORIC ACID, 8 (6.1), II
Transport document description (ADN) :	UN 1790, HYDROFLUORIC ACID, 8 (6.1), II
Transport document description (RID) :	UN 1790, HYDROFLUORIC ACID, 8 (6.1), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
IMDG
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
IATA
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
ADN
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
RID
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CT1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4DH Tank special provisions (ADR) : TU14, TE21 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Hazard identification number (Kemler No.) : 86 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2W APP code : B
- Transport by sea
Packing instructions (IMDG) : P001 Special packing provisions (IMDG) : PP81 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : D Stowage and handling (IMDG) : SW1, SW2, H2 Properties and observations (IMDG) : Colourless liquid with an irritating odour. Highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Both the liquid and its fumes cause severe burns to skin, eyes and mucous membranes. MFAG-No : 157
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8P
- Inland waterway transport
Classification code (ADN) : CT1 Special provisions (ADN) : 802 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : CT1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T8 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4DH Special provisions for RID tanks (RID) : TU14, TE17, TE21, TT4 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 86
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : None of the components are listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements: Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1 Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1 Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A H300 Fatal if swallowed. H310 Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H330 Fatal if inhaled. H331 Toxic if inhaled.