SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	PERCHLORIC ACID 70% AR
Catalogue No. :	AL3445	Product form :	Mixture
CAS Number :	7601-90-3	EC Number :	231-512-4
Grade :		EC Index Number :	017-006-00-4
Chemical Formula :	HClO4	HSN Code :	28111990
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS03 GHS05 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H271 - May cause fire or explosion; strong oxidiser. H290 - May be corrosive to metals. H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective clothing, face protection, eye protection, protective gloves. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370+P378 - In case of fire: Use ... to extinguish. P371+P380+P375 - In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		7601-90-3
EC Index No. :		017-006-00-4
EC No. :		231-512-4
3.2. Mixture
Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Perchloric acid	(CAS-No.) 7601-90-3 (EC-No.) 231-512-4 (EC Index-No.) 017-006-00-4	<= 70	Ox. Liq. 1, H271 Skin Corr. 1A, H314 Eye Dam. 1, H318
Water	(CAS-No.) 7732-18-5 (EC-No.) 231-791-2	29 - 30	Not classified	Full text of H-statements: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Wash with plenty of water/…. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. May cause damage to organs. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	May cause fire or explosion; strong oxidiser.
Explosion hazard :	Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Hazardous waste due to potential risk of explosion. May be corrosive to metals.
Precautions for safe handling :	Do not breathe vapours. Avoid contact with skin and eyes. Avoid contact during pregnancy/while nursing. Keep away from sources of ignition - No smoking.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	100.46 g/mol
Colour :	Clear Colorless.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-18 °C
Freezing point :	No data available
Boiling point :	203 °C
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	9 hPa at 20 °C
Relative vapour density at 20°C :	3.5
Density :	1.664 at 25°C
Solubility :	Water: Infinitely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	Heating may cause an explosion.
Oxidising properties :	The substance or mixture is classified as oxidizin
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
May cause fire or explosion; strong oxidiser.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Heat. Sparks. Open flame.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. ATE CLP (oral) 500 mg/kg bodyweight
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1873
UN-No. (IMDG) :	1873
UN-No. (IATA) :	1873
UN-No. (ADN) :	1873
UN-No. (RID) :	1873
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	PERCHLORIC ACID
Proper Shipping Name (IMDG) :	PERCHLORIC ACID
Proper Shipping Name (IATA) :	PERCHLORIC ACID
Proper Shipping Name (ADN) :	PERCHLORIC ACID
Proper Shipping Name (RID) :	PERCHLORIC ACID
Transport document description (ADR) :	UN 1873, PERCHLORIC ACID, 5.1 (8), I
Transport document description (IMDG) :	UN 1873, PERCHLORIC ACID, 5.1 (8), I
Transport document description (IATA) :	UN 1873, PERCHLORIC ACID, 5.1 (8), I
Transport document description (ADN) :	UN 1873, PERCHLORIC ACID, 5.1 (8), I
Transport document description (RID) :	UN 1873, PERCHLORIC ACID, 5.1 (8), I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	5.1 (8)
Danger labels :	5.1, 8
IMDG
Transport hazard class(es) :	5.1 (8)
Danger labels :	5.1, 8
IATA
Transport hazard class(es) :	5.1 (8)
Danger labels :	5.1, 8
ADN
Transport hazard class(es) :	5.1 (8)
Danger labels :	5.1, 8
RID
Transport hazard class(es) :	5.1 (8)
Danger labels :	5.1, 8
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OC1 Special provisions (ADR) : 60 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P502 Special packing provisions (ADR) : PP28 Mixed packing provisions (ADR) : MP3 Portable tank and bulk container instructions (ADR) : T10 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : L4DN(+) Tank special provisions (ADR) : TU3, TU28 Vehicle for tank carriage : AT Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24 Special provisions for carriage - Operation (ADR) : S20 Hazard identification number (Kemler No.) : 558 Orange plates : Tunnel restriction code (ADR) : B/E EAC code : 2P
- Transport by sea
Special provisions (IMDG) : 900 Packing instructions (IMDG) : P502 Special packing provisions (IMDG) : PP28 Tank instructions (IMDG) : T10 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-Q Stowage category (IMDG) : D Segregation (IMDG) : SG16 Properties and observations (IMDG) : Colourless liquid.Mixtures with combustible material may ignite spontaneously and, when involved in a fire, by shock or by friction, may cause an explosion. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Transport of PERCHLORIC ACID with more than 72% acid, by mass is prohibited. MFAG-No : 143
- Air transport
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 553 CAO max net quantity (IATA) : 2.5L ERG code (IATA) : 5C
- Inland waterway transport
Classification code (ADN) : OC1 Special provisions (ADN) : 60 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : OC1 Special provisions (RID) : 60 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P502 Special packing provisions (RID) : PP28 Mixed packing provisions (RID) : MP3 Portable tank and bulk container instructions (RID) : T10 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : L4DN(+) Special provisions for RID tanks (RID) : TU3, TU28, TE16 Transport category (RID) : 1 Special provisions for carriage - Loading, unloading and handling (RID) : CW24 Hazard identification number (RID) : 558
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen -Borstvoeding : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen - Ontwikkeling : None of the components are listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Met. Corr. 1 Corrosive to metals, Category 1 Ox. Liq. 1 Oxidising Liquids, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H271 May cause fire or explosion; strong oxidiser. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure.