SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	PERCHLORIC ACID 20% AR
Catalogue No. :	AL3442	Product form :	Mixture
CAS Number :	7601-90-3	EC Number :	231-512-4
Grade :		EC Index Number :
Chemical Formula :	HClO4	HSN Code :	28111990
Synonyms :	PCA
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS03 GHS05 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H272 - May intensify fire; oxidiser. H290 - May be corrosive to metals. H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 - Wear protective gloves, protective clothing, face protection, eye protection. P301+P312 - IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P330 - Rinse mouth. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		7601-90-3
EC No. :		231-512-4
3.2. Mixture
Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
ACETIC ACID GLACIAL AR	(CAS-No.) 64-19-7 (EC-No.) 200-580-7 (EC Index-No.) 607-002-00-6	80	Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Skin Corr. 1A, H314 Eye Dam. 1, H318
Perchloric acid	(CAS-No.) 7601-90-3 20 Skin Corr. 1B, H314
Full text of H-statements: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Wash with plenty of water/…. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. May cause damage to organs. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	May intensify fire; oxidiser.
Explosion hazard :	May cause fire or explosion; strong oxidiser.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	May be corrosive to metals.
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Use only non-sparking tools. Ground/bond container and receiving equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Colourless.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	104 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	1.12 g/cm3
Solubility :	No data available
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Heat. Open flame. Sparks.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. ATE CLP (oral) 500 mg/kg bodyweight
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	ACETIC ACID GLACIAL AR (64-19-7) Persistence and degradability Not established.
12.3 Bioaccumulative potential
Bioaccumulative potential :	ACETIC ACID GLACIAL AR (64-19-7) Log Pow 0.17 Bioaccumulative potential Not established.
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1802
UN-No. (IMDG) :	1802
UN-No. (IATA) :	1802
UN-No. (ADN) :	1802
UN-No. (RID) :	1802
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	PERCHLORIC ACID
Proper Shipping Name (IMDG) :	PERCHLORIC ACID
Proper Shipping Name (IATA) :	PERCHLORIC ACID
Proper Shipping Name (ADN) :	PERCHLORIC ACID
Proper Shipping Name (RID) :	PERCHLORIC ACID
Transport document description (ADR) :	UN 1802, PERCHLORIC ACID, 8 (5.1), II
Transport document description (IMDG) :	UN 1802, PERCHLORIC ACID, 8 (5.1), II
Transport document description (IATA) :	UN 1802, PERCHLORIC ACID, 8 (5.1), II
Transport document description (ADN) :	UN 1802, PERCHLORIC ACID, 8 (5.1), II
Transport document description (RID) :	UN 1802, PERCHLORIC ACID, 8 (5.1), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (5.1)
Danger labels :	8, 5.1
IMDG
Transport hazard class(es) :	8 (5.1)
Danger labels :	8, 5.1
IATA
Transport hazard class(es) :	8 (5.1)
Danger labels :	8, 5.1
ADN
Transport hazard class(es) :	8 (5.1)
Danger labels :	8, 5.1
RID
Transport hazard class(es) :	8 (5.1)
Danger labels :	8, 5.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CO1 Special provisions (ADR) : 522 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP3 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24 Hazard identification number (Kemler No.) : 85 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2P
- Transport by sea
Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q Stowage category (IMDG) : C Segregation (IMDG) : SG16 Properties and observations (IMDG) : Colourless liquid.Oxidant. Highly corrosive to most metals. MFAG-No : 140
- Air transport
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L Special provisions (IATA) : A1 ERG code (IATA) : 8X
- Inland waterway transport
Classification code (ADN) : CO1 Special provisions (ADN) : 522 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : CO1 Special provisions (RID) : 522 Limited quantities (RID) : 1L Excepted quantities (RID) : E0 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP3 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW24 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 85
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, Slightly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen -Borstvoeding : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen -Ontwikkeling : None of the components are listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 Met. Corr. 1 Corrosive to metals, Category 1 Ox. Liq. 2 Oxidising Liquids, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H226 Flammable liquid and vapour. H272 May intensify fire; oxidiser. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H332 Harmful if inhaled. H373 May cause damage to organs through prolonged or repeated exposure.