SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	Acetic Acid Glacial AR (Aldehyde Free)
Catalogue No. :	AL0021	Product form :	Substance
CAS Number :	64-19-7	EC Number :	200-580-7
Grade :		EC Index Number :	607-002-00-6
Chemical Formula :		HSN Code :	29152100
Synonyms :	Ethanoic Acid
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial;For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Skin corrosion/irritation, Category 1A H314 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
R10 C; R35 Full text of R-phrases: see section 16 Specific concentration limits: (10 =< C < 25) Xi;R36/38 (25 =< C < 90) C;R34 (C >= 90) C;R35
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP) :	P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		Not applicable
CAS No. :		64-19-7
EC Index No. :		607-002-00-6
EC No. :		200-580-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Prevent entry to sewers and public waters. Avoid release to the environment. Harmful to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	See Heading 8. Exposure controls and personal protection

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin, eyes and clothing. Do not breathe vapours.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in original container. Keep container tightly closed. Store in a well-ventilated place. Incompatible products : Strong bases. Strong acids.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	60.05 g/mol
Colour :	Clear Colorless.
Odour :	strong, vinegar-like.
Odour threshold :	No data available
pH value :	2.4
Relative evaporation rate (butylacetate=1) :	0.97
Melting point :	16.2 °C
Freezing point :	No data available
Boiling point :	117 - 118
Flash point :	40 °C
Auto-ignition temperature :	485 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour
Vapour pressure :	15.2 hPa at 20°C
Relative vapour density at 20°C :	2.1
Density :	1.049 g/cm3
Solubility :	Water: Complete
Log Pow :	0.17
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.04 - 0.199 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
Not established.
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases. Thermal decomposition generate

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 2.4
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 2.4
Respiratory or skin sensitisation :	Not classified Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity :	Not classified Based on available data, the classification criteria are not met
Carcinogenicity :	Not classified Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity :	Not classified Additional information : Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) :	Not classified Additional information
Specific target organ toxicity (repeated exposure) :	Not classified Additional information

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	Acetic Acid Glacial AR (Aldehyde Free) (64-19-7) Persistence and degradability Not established.
12.3 Bioaccumulative potential
Bioaccumulative potential :	Acetic Acid Glacial AR (Aldehyde Free) (64-19-7) Log Pow 0.17 Bioaccumulative potential Not established.
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	Additional information : Avoid release to the environment

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Avoid release to the environment.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2789
UN-No. (IMDG) :	2789
UN-No. (IATA) :	2789
UN-No. (ADN) :	2789
UN-No. (RID) :	2789
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ACETIC ACID, GLACIAL
Proper Shipping Name (IMDG) :	ACETIC ACID, GLACIAL
Proper Shipping Name (IATA) :	ACETIC ACID, GLACIAL
Proper Shipping Name (ADN) :	ACETIC ACID, GLACIAL
Proper Shipping Name (RID) :	ACETIC ACID, GLACIAL
Transport document description (ADR) :	UN 2789, ACETIC ACID, GLACIAL, 8 (3), II
Transport document description (IMDG) :	UN 2789, ACETIC ACID, GLACIAL, 8 (3), II
Transport document description (IATA) :	UN 2789, ACETIC ACID, GLACIAL, 8 (3), II
Transport document description (ADN) :	UN 2789, ACETIC ACID, GLACIAL, 8 (3), II
Transport document description (RID) :	UN 2789, ACETIC ACID, GLACIAL, 8 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IMDG
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IATA
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
ADN
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
RID
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CF1 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 83 Acetic Acid Glacial AR (Ald Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2P APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : A
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8F
- Inland waterway transport
Classification code (ADN) : CF1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : CF1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 83
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Acetic Acid Glacial AR (Aldehyde Free) is not on the REACH Candidate List Acetic Acid Glacial AR (Aldehyde Free) is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 93) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No chemical safety assessment has been carried out

SECTION 16: Other Information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of R-, H- and EUH-phrases: Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A H226 Flammable liquid and vapour H314 Causes severe skin burns and eye damage R10 Flammable R35 Causes severe burns C Corrosive