SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	2,4-DICHLOROPHENOXY ACETIC ACID
Catalogue No. :	AL1726	Product form :	Substance
CAS Number :	94-75-7	EC Number :	202-361-1
Grade :		EC Index Number :	607-039-00-8
Chemical Formula :		HSN Code :	29189900
Synonyms :	2,4-D Acid
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Serious eye damage/eye irritation, Category 1 H318 Acute toxicity (oral), Category 4 H302 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Skin sensitisation, Category 1 H317 Hazardous to the aquatic H412 environment Chronic Hazard, Category 3 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R22 Xi; R41 Xi; R37 R43 R52/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS07
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H302 - Harmful if swallowed. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H335 - May cause respiratory irritation. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P280 - Wear protective gloves, protective clothing, eye protection, face protection. P261 - Avoid breathing vapours, dust, fume, gas. P273 - Avoid release to the environment.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		2,4-DICHLOROPHENOXY ACETIC ACID For Synthesis
CAS No. :		94-75-7
EC Index No. :		607-039-00-8
EC No. :		202-361-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of water/…. Get medical advice/attention. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause an allergic skin reaction. May cause respiratory irritation. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Harmful to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	221.04 g/mol
Colour :	White powder.
Odour :	No data available
Odour threshold :	3.13 ppm
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	136 - 140 °C
Freezing point :	No data available
Boiling point :	160 °C
Flash point :	No data available
Auto-ignition temperature :	> 180 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	< 1 hPa at 20°C
Relative vapour density at 20°C :	No data available
Density :	1.416 g/cm3
Solubility :	Water: Insoluble
Log Pow :	2.8
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	2,4-DICHLOROPHENOXY ACETIC ACID For Synthesis (94-75-7) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	2,4-DICHLOROPHENOXY ACETIC ACID For Synthesis (94-75-7) Log Pow 2.8
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3077
UN-No. (IMDG) :	3077
UN-No. (IATA) :	3077
UN-No. (ADN) :	3077
UN-No. (RID) :	3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (ADN) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (IMDG) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (IATA) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (ADN) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (RID) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	9
Danger labels :	9
IMDG
Transport hazard class(es) :	9
Danger labels :	9
IATA
Transport hazard class(es) :	9
Danger labels :	9
ADN
Transport hazard class(es) :	9
Danger labels :	9
RID
Transport hazard class(es) :	9
Danger labels :	9
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M7 Special provisions (ADR) : 274, 335, 375, 601 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : PP12, B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1, BK1, BK2, BK3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV, LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V13 Special provisions for carriage - Bulk (ADR) : VC1, VC2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : - EAC code : 2Z
- Transport by sea
Special provisions (IMDG) : 274, 335, 966, 967, 969 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : LP02, P002 Special packing provisions (IMDG) : PP12 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : BK1, BK2, BK3, T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F Stowage category (IMDG) : A Stowage and handling (IMDG) : SW23 MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y956 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 956 PCA max net quantity (IATA) : 400kg CAO packing instructions (IATA) : 956 CAO max net quantity (IATA) : 400kg Special provisions (IATA) : A97, A158, A179, A197 ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M7 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T* B** Equipment required (ADN) : PP, A Number of blue cones/lights (ADN) : 0 Additional requirements/Remarks (ADN) : * Only in the molten state. ** For carriage in bulk see also 7.1.4.1. ** * Only in the case of transport in bulk.
- Rail transport
Classification code (RID) : M7 Special provisions (RID) : 274, 335, 375, 601 Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : PP12, B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1, BK1, BK2, BK3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV, LGBV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W13 Special provisions for carriage – Bulk (RID) : VC1, VC2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW31 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 2,4-DICHLOROPHENOXY ACETIC ACID For Synthesis is not on the REACH Candidate List 2,4-DICHLOROPHENOXY ACETIC ACID For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 1177) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Sens. 1 Skin sensitisation, Category 1 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. R22 Harmful if swallowed R37 Irritating to respiratory system R41 Risk of serious damage to eyes R43 May cause sensitisation by skin contact R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Xi Irritant Xn Harmful