SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	CHLORO ACETIC ACID (tri) AR (trichloro acetic acid)
Catalogue No. :	AL1254	Product form :	Substance
CAS Number :	76-03-9	EC Number :	200-927-2
Grade :		EC Index Number :	607-004-00-7
Chemical Formula :		HSN Code :	29154030
Synonyms :	trichloro acetic acid
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 1A H314 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R35 N; R50/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H314 - Causes severe skin burns and eye damage. H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		TRICHLOROACETIC ACID AR
CAS No. :		76-03-9
EC Index No. :		607-004-00-7
EC No. :		200-927-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Emergency procedures	Stop release
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean contaminated surfaces with an excess of water.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures :	Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	163.39 g/mol
Colour :	Colorless crystals.
Odour :	No data available
Odour threshold :	No data available
pH value :	1
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	54 - 58 °C
Freezing point :	No data available
Boiling point :	196 °C
Flash point :	> 113 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	5.64
Density :	1.6 g/cm3
Solubility :	Water: Soluble in water
Log Pow :	1.645
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 1
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 1
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	TRICHLOROACETIC ACID AR (76-03-9) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	TRICHLOROACETIC ACID AR (76-03-9) Log Pow 1.645
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1839
UN-No. (IMDG) :	1839
UN-No. (IATA) :	1839
UN-No. (ADN) :	1839
UN-No. (RID) :	1839
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	TRICHLOROACETIC ACID
Proper Shipping Name (IMDG) :	TRICHLOROACETIC ACID
Proper Shipping Name (IATA) :	TRICHLOROACETIC ACID
Proper Shipping Name (ADN) :	TRICHLOROACETIC ACID
Proper Shipping Name (RID) :	TRICHLOROACETIC ACID
Transport document description (ADR) :	UN 1839, TRICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1839, TRICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1839, TRICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1839, TRICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1839, TRICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8
Danger labels :	8
IMDG
Transport hazard class(es) :	8
Danger labels :	8
IATA
Transport hazard class(es) :	8
Danger labels :	8
ADN
Transport hazard class(es) :	8
Danger labels :	8
RID
Transport hazard class(es) :	8
Danger labels :	8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C4 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E2 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN, L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X
- Transport by sea
Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B21, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Properties and observations (IMDG) : Colourless, deliquescent crystals. Melting point of the pure substance: 58°C . In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y844 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 859 PCA max net quantity (IATA) : 15kg CAO packing instructions (IATA) : 863 CAO max net quantity (IATA) : 50kg ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C4 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C4 Excepted quantities (RID) : E2 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN, L4BN Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions TRICHLOROACETIC ACID AR is not on the REACH Candidate List TRICHLOROACETIC ACID AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, Significantly hazardous to water (Classification according to AwSV; ID No. 197) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : TRICHLOROACETIC ACID AR is listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A H314 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects. R35 Causes severe burns R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment C Corrosive N Dangerous for the environment