SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	Acrylonitrile 99%
Catalogue No. :	AL0111	Product form :	Substance
CAS Number :	107-13-1	EC Number :	203-466-5
Grade :		EC Index Number :	608-003-00-4
Chemical Formula :	C3H3N	HSN Code :	29261000
Synonyms :	Vinyl cyanide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Carcinogenicity, Category 1B H350 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Serious eye damage/eye H318 irritation, Category 1 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Sensitisation Skin, category 1 H317 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45 F; R11 T; R23/24/25 Xi; R41 Xi; R37/38 R43 N; R51/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS06 GHS02 GHS05 GHS08 GHS09
Signal word (CLP) :	-
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H335 - May cause respiratory irritation H350 - May cause cancer H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		ACRYLONITRILE (Stabilised) 99% Extra Pure
CAS No. :		107-13-1
EC Index No. :		608-003-00-4
EC No. :		203-466-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Take off contaminated clothing. Gently wash with plenty of soap and water. Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after inhalation : Toxic if inhaled. May cause respiratory irritation. Symptoms/injuries after skin contact : Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Toxic if swallowed. Chronic symptoms : May cause cancer.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). earth, sand, dry chemical powder or foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream. dry chemical powder.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture. Hazardous decomposition products in case of fire : Thermal decomposition generates : Toxic fumes may be released.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Use only non-sparking tools. Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	53.06 g/mol
Colour :	Clear Colorless.
Odour :	mild peach kernels.
Odour threshold :	21.4 ppm
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-830 °C
Freezing point :	No data available
Boiling point :	77.3 °C
Flash point :	5 °C Critical temperature : 262.78 °C
Auto-ignition temperature :	481 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Highly flammable liquid and vapour
Vapour pressure :	11.1 kPa
Relative vapour density at 20°C :	No data available
Relative density :	No data available Density : 0.806 g/cm3
Density :	0.806 g/cm3 Relative gas density : 1.8
Relative gas density :	1.8
Solubility :	Water: slightly soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.03 - 0.17 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Flammable liquid and vapour.
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	May cause cancer.
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects
12.2 Persistence - degradability
Persistence - degradability :	Acrylonitrile 99% (107-13-1) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1093
UN-No. (IMDG) :	1093
UN-No. (IATA) :	1093
UN-No. (ADN) :	1093
UN-No. (RID) :	1093
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ACRYLONITRILE, STABILIZED
Proper Shipping Name (IMDG) :	ACRYLONITRILE, STABILIZED
Proper Shipping Name (IATA) :	ACRYLONITRILE, STABILIZED
Proper Shipping Name (ADN) :	ACRYLONITRILE, STABILIZED
Proper Shipping Name (RID) :	ACRYLONITRILE, STABILIZED
Transport document description (ADR) :	UN 1093, ACRYLONITRILE, STABILIZED, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1093, ACRYLONITRILE, STABILIZED, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1093, ACRYLONITRILE, STABILIZED, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1093, ACRYLONITRILE, STABILIZED, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1093, ACRYLONITRILE, STABILIZED, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
IMDG
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
IATA
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
ADN
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
RID
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FT1 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001 Mixed packing provisions (ADR) : MP7, MP17 Portable tank and bulk container instructions (ADR) : T14 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE21 Vehicle for tank carriage : FL Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S22 Hazard identification number (Kemler No.) : 336 Orange plates : Tunnel restriction code (ADR) : C/E EAC code : •3WE APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P001 Tank instructions (IMDG) : T14 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : E Stowage and handling (IMDG) : SW2 Flash point (IMDG) : -5°C c.c. MFAG-No : 131P
- Air transport
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 361 CAO max net quantity (IATA) : 30L ERG code (IATA) : 3P
- Inland waterway transport
Classification code (ADN) : FT1 Special provisions (ADN) : 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : FT1 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P001 Mixed packing provisions (RID) : MP7, MP17 Portable tank and bulk container instructions (RID) : T14 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28 Hazard identification number (RID) : 336
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Acrylonitrile 99% is not on the REACH Candidate List Acrylonitrile 99% is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 10) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Carc. 1B Carcinogenicity, Category 1B Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation — Skin, category 1 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour H301 Toxic if swallowed H311 Toxic in contact with skin H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H335 May cause respiratory irritation H350 May cause cancer H411 Toxic to aquatic life with long lasting effects R11 Highly flammable R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R43 May cause sensitisation by skin contact R45 May cause cancer R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment F Highly flammable N Dangerous for the environment T Toxic Xi Irritant