2-CHLOROETHANOL Extra Pure

2-CHLOROETHANOL Extra Pure

Synonyms : Ethylene chlorohydrin

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : ETHYLENE CHLOROHYDRINE (2-chloroethanol)
Catalogue No. : AL2070 Product form : Substance
CAS Number : 107-07-3 EC Number : 203-459-7
Grade : EC Index Number : 603-028-00-7
Chemical Formula : HSN Code : 29051690
Synonyms : Ethylene chlorohydrin
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids,
Category 3
H226
Acute toxicity (oral),
Category 1
H300
Acute toxicity (dermal),
Category 1
H310
Acute toxicity (inhal.),
Category 2
H330
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T+; R26/27/28
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS06GHS06
Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour
H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled
Precautionary statements (CLP) : P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P264 - Wash ... thoroughly after handling
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 2-CHLOROETHANOL Extra Pure
CAS No. : 107-07-3
EC Index No. : 603-028-00-7
EC No. : 203-459-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after inhalation : Fatal if inhaled.
Symptoms/injuries after skin contact : Fatal in contact with skin.
Symptoms/injuries after ingestion : Fatal if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing.
Hygiene measures : Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 80.51 g/mol
Colour : Clear Colorless.
Odour : sweet pleasant.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -89 °C
Freezing point : No data available
Boiling point : 129 °C
Flash point : 55 °C
Auto-ignition temperature : 425 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 7 hPa at 20 °C
Relative vapour density at 20°C : 2.78
Density : 1.2 g/cm3
Solubility : Water: Easily soluble in cold water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.05 - 0.16 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions. Flammable liquid and vapour.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Fatal if swallowed. Dermal: Fatal in contact with skin. Inhalation: Fatal if
inhaled.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Fatal if swallowed. Fatal in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1135
UN-No. (IMDG) : 1135
UN-No. (IATA) : 1135
UN-No. (ADN) : 1135
UN-No. (RID) : 1135
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ETHYLENE CHLOROHYDRIN
Proper Shipping Name (IMDG) : ETHYLENE CHLOROHYDRIN
Proper Shipping Name (IATA) : ETHYLENE CHLOROHYDRIN
Proper Shipping Name (ADN) : ETHYLENE CHLOROHYDRIN
Proper Shipping Name (RID) : ETHYLENE CHLOROHYDRIN
Transport document description (ADR) : UN 1135, ETHYLENE CHLOROHYDRIN, 6.1 (3), I
Transport document description (IMDG) : UN 1135, ETHYLENE CHLOROHYDRIN, 6.1 (3), I
Transport document description (IATA) : UN 1135, ETHYLENE CHLOROHYDRIN, 6.1 (3), I
Transport document description (ADN) : UN 1135, ETHYLENE CHLOROHYDRIN, 6.1 (3), I
Transport document description (RID) : UN 1135, ETHYLENE CHLOROHYDRIN, 6.1 (3), I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
IMDG
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
IATA
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
ADN
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
RID
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1
Special provision (ADR) : 354
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P602
Mixed packing provisions (ADR) : MP8, MP17
Portable tank and bulk container
instructions (ADR)
: T20
Portable tank and bulk container special
provisions (ADR)
: TP2, TP37
Tank code (ADR) : L10CH
Tank special provisions (ADR) : TU14, TU15, TE19, TE21
Vehicle for tank carriage : FL
Transport category (ADR) : 1
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV1, CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S2, S9, S14
Hazard identification number (Kemler No.) : 663
Orange plates :
Tunnel restriction code (ADR) : C/D
EAC code : •2W
APP code : A(fl)
- Transport by sea
Special provision (IMDG) : 354
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P602
Tank instructions (IMDG) : T20
Tank special provisions (IMDG) : TP2, TP13, TP37
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : D
Stowage and handling (IMDG) : SW2
Flash point (IMDG) : 60°C o.c.
MFAG-No : 131
- Air transport
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : Forbidden
PCA max net quantity (IATA) : Forbidden
CAO packing instructions (IATA) : Forbidden
CAO max net quantity (IATA) : Forbidden
ERG code (IATA) : 6F
- Inland waterway transport
Classification code (ADN) : TF1
Special provisions (ADN) : 354, 802
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, EX, TOX, A
Ventilation (ADN) : VE01, VE02
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TF1
Special provision (RID) : 354
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P602
Mixed packing provisions (RID) : MP8, MP17
Portable tank and bulk container
instructions (RID)
: T20
Portable tank and bulk container special
provisions (RID)
: TP2, TP37
Tank codes for RID tanks (RID) : L10CH
Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22
Transport category (RID) : 1
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW28, CW31
Hazard identification number (RID) : 663
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
2-CHLOROETHANOL Extra Pure is not on the REACH Candidate List
2-CHLOROETHANOL Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to VwVwS, Annex 2; WGK No 229)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 ; Emergency management guidelines for the
storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1
Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Flam. Liq. 3 Flammable liquids, Category 3
H226 Flammable liquid and vapour
H300 Fatal if swallowed
H310 Fatal in contact with skin
H330 Fatal if inhaled
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed
T+ Very toxic