2-DIETHYLAMINOETHANOL For Synthesis

2-DIETHYLAMINOETHANOL For Synthesis

Synonyms : N,N-Diethylethanolamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : N,N-DIETHYL ETHANOLAMINE
Catalogue No. : AL1764 Product form : Substance
CAS Number : 100-37-8 EC Number : 202-845-2
Grade : EC Index Number : 603-048-00-6
Chemical Formula : HSN Code : 29221990
Synonyms : N,N-Diethylethanolamine
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation,
Category 1B
H314
Serious eye damage/eye
irritation, Category 1
H318
Flammable liquids,
Category 3
H226
Acute toxicity (dermal),
Category 4
H312
Acute toxicity (inhal.),
Category 4
H332
Acute toxicity (oral),
Category 4
H302
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20/21/22
C; R34
R10
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS05GHS05 GHS02GHS02 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour
H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP) : P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
EUH phrases : EUH071 - Corrosive to the respiratory tract
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 2-DIETHYLAMINOETHANOL FOR SYNTHESIS
CAS No. : 100-37-8
EC Index No. : 603-048-00-6
EC No. : 202-845-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician. Specific treatment is
urgent (see ... on this label).
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Immediately call a POISON CENTER or doctor/physician. Specific
measures (see ... on this label). Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/physician. Specific treatment (see ... on this label).
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. Do
NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.
Specific treatment (see ... on this label).
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after inhalation : Corrosive to the respiratory tract.
Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Harmful in contact with skin.
Symptoms/injuries after eye contact : Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked
lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : No naked lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting/… equipment. Comply with applicable regulations.
Storage conditions : Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection :
Respiratory protection :

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : No data available
Odour threshold : No data available
pH value : 10
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -70 °C
Freezing point : No data available
Boiling point : 158 - 161
Flash point : 50 °C
Auto-ignition temperature : 320 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour
Vapour pressure : 1 hPa at 20 °C
Relative vapour density at 20°C : 4.05
Solubility : Water: Soluble in water
Log Pow : 0.3
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.014 - 0.117 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled. Oral: Harmful if
swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 10
Serious eye damage/irritation : Causes serious eye damage.
pH: 10
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified Additional information
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : 2-DIETHYLAMINOETHANOL FOR SYNTHESIS (100-37-8) Log Pow 0.3
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2686
UN-No. (IMDG) : 2686
UN-No. (IATA) : 2686
UN-No. (ADN) : 2686
UN-No. (RID) : 2686
14.2. UN proper shipping name
Proper Shipping Name (ADR) : 2-DIETHYLAMINO-ETHANOL
Proper Shipping Name (IMDG) : 2-DIETHYLAMINO-ETHANOL
Proper Shipping Name (IATA) : 2-DIETHYLAMINO-ETHANOL
Proper Shipping Name (ADN) : 2-DIETHYLAMINO-ETHANOL
Proper Shipping Name (RID) : 2-DIETHYLAMINO-ETHANOL
Transport document description (ADR) : UN 2686, 2-DIETHYLAMINO-ETHANOL, 8 (3), II
Transport document description (IMDG) : UN 2686, 2-DIETHYLAMINO-ETHANOL, 8 (3), II
Transport document description (IATA) : UN 2686, 2-DIETHYLAMINO-ETHANOL, 8 (3), II
Transport document description (ADN) : UN 2686, 2-DIETHYLAMINO-ETHANOL, 8 (3), II
Transport document description (RID) : UN 2686, 2-DIETHYLAMINO-ETHANOL, 8 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
IMDG
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
IATA
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
ADN
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
RID
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CF1
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BN
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Operation
(ADR)
: S2
Hazard identification number (Kemler No.) : 83
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2W
APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : A
Flash point (IMDG) : 46°C to 60°C c.c.
MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
ERG code (IATA) : 8F
- Inland waterway transport
Classification code (ADN) : CF1
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : CF1
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 83
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
2-DIETHYLAMINOETHANOL FOR SYNTHESIS is not on the REACH Candidate List
2-DIETHYLAMINOETHANOL FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to
VwVwS, Annex 2; WGK No 1288)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 ; Emergency management guidelines for the
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 ; Emergency management guidelines for the
storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Flam. Liq. 3 Flammable liquids, Category 3
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H332 Harmful if inhaled
EUH071 Corrosive to the respiratory tract
R10 Flammable
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R34 Causes burns
C Corrosive
Xn Harmful