SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	DIETHYLENE GLYCOL AR (digol)
Catalogue No. :	AL1755	Product form :	Substance
CAS Number :	111-46-6	EC Number :	203-872-2
Grade :		EC Index Number :	603-140-00-6
Chemical Formula :		HSN Code :	29094100
Synonyms :	Digol
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial Intermediate
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20 Xn; R22 R19 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07
Signal word (CLP) :	Warning
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		DIETHYLENE GLYCOL AR
CAS No. :		111-46-6
EC Index No. :		603-140-00-6
EC No. :		203-872-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). 5.2. Special hazards arising from the substance or mixture Explosion hazard : May form flammable/explosive vapour-air mixture. Heat
Unsuitable extinguishing media :
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard :	May form flammable/explosive vapour-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. May form explosive peroxides.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	No open flames. No smoking. Use special care to avoid static electric charges. Remove ignition sources.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
No additional information available
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Hazardous waste due to potential risk of explosion.
Precautions for safe handling :	Keep away from sources of ignition - No smoking. No open flames. No smoking.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed.
Storage conditions :	Keep in fireproof place. Incompatible products : Oxidizing agent.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :
Eye protection :
Skin and body protection :
Respiratory protection :

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	odourless.
Odour threshold :	No data available
pH value :	5 - 8 at 500 g/l at 20 °C
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-10 °C
Freezing point :	No data available
Boiling point :	123 °C
Flash point :	123 °C
Auto-ignition temperature :	229 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	0.04 hPa at 20 °C
Relative vapour density at 20°C :	3.66
Density :	1.118 g/ml at 25 °C
Solubility :	Water: Infinitely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	May form explosive peroxides.
Oxidising properties :	No data available
Explosive limits :	0.02 - 0.123 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
No additional information available
10.3 Possibility of hazardous reactions
Reacts vigorously with strong oxidizers and acids.
10.4 Conditions to avoid
Heat. Sparks. Open flame. Direct sunlight. Overheating.
10.5 Incompatible materials
Oxidizing agent.
10.6 Hazardous decomposition products
May form explosive peroxides.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Inhalation: Harmful if inhaled. Oral: Harmful if swallowed.
Skin corrosion/irritation :	Not classified pH: 5 - 8 at 500 g/l at 20 °C
Serious eye damage/irritation :	Not classified pH: 5 - 8 at 500 g/l at 20 °C
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	Not applicable
UN-No. (IMDG) :	Not applicable
UN-No. (IATA) :	Not applicable
UN-No. (ADN) :	Not applicable
UN-No. (RID) :	Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	Not applicable
Proper Shipping Name (IMDG) :	Not applicable
Proper Shipping Name (IATA) :	Not applicable
Proper Shipping Name (ADN) :	Not applicable
Proper Shipping Name (RID) :	Not applicable
Transport document description (ADR) :	Not applicable
Transport document description (IMDG) :	Not applicable
Transport document description (IATA) :	Not applicable
Transport document description (ADN) :	Not applicable
Transport document description (RID) :	Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	Not applicable
IMDG
Transport hazard class(es) :	Not applicable
IATA
Transport hazard class(es) :	Not applicable
ADN
Transport hazard class(es) :	Not applicable
RID
Transport hazard class(es) :	Not applicable
14.4. Packing group
Packing group (ADR) :	Not applicable
Packing group (IMDG) :	Not applicable
Packing group (IATA) :	Not applicable
Packing group (ADN) :	Not applicable
Packing group (RID) :	Not applicable
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions DIETHYLENE GLYCOL AR is not on the REACH Candidate List DIETHYLENE GLYCOL AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 79) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information
Full text of R-, H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 H302 Harmful if swallowed. H332 Harmful if inhaled. EUH019 May form explosive peroxides. R19 May form explosive peroxides R20 Harmful by inhalation R22 Harmful if swallowed Xn Harmful