SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	LEAD DIOXIDE AR
Catalogue No. :	AL2702	Product form :	Substance
CAS Number :	1309-60-0	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	28249000
Synonyms :	Lead(IV) oxide; Lead (su)peroxide; Lead peroxide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, Category 2 H272 Acute toxicity (oral), Category 4 H302 Acute toxicity (inhalation:dust,mist) Category 4 H332 Reproductive toxicity, Category 1A H360Df Specific target organ toxicity Repeated exposure, Category 1 H372 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; T; N; R20/22-33-50/53-61-62 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS03 GHS07 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H272 - May intensify fire; oxidiser H302+H332 - Harmful if swallowed or if inhaled H360Df - May damage the unborn child. Suspected of damaging fertility H372 - Causes damage to organs through prolonged or repeated exposure H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P220 - Keep/Store away from clothing/¦/combustible materials P273 - Avoid release to the environment P308+P313 - IF exposed or concerned: Get medical advice/attention P501 - Dispose of contents/container to ...
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		LEAD DIOXIDE AR
CAS No. :		1309-60-0
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : May damage the unborn child. Suspected of damaging fertility. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : Harmful if inhaled. Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray. dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	May intensify fire; oxidiser.
Explosion hazard :	Heating may cause an explosion.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Colour
Colour :	Dark brown.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	2900 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	8.2
Density :	9.38 g/cm3
Solubility :	No data available
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	The substance or mixture is classified as oxidizin
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
May cause or intensify fire; oxidizer.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Inhalation:dust/mist: Harmful if inhaled.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	May damage the unborn child. Suspected of damaging fertility.
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure. Additional information
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	LEAD DIOXIDE AR (1309-60-0) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1872
UN-No. (IMDG) :	1872
UN-No. (IATA) :	1872
UN-No. (ADN) :	1872
UN-No. (RID) :	1872
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	LEAD DIOXIDE
Proper Shipping Name (IMDG) :	LEAD DIOXIDE
Proper Shipping Name (IATA) :	LEAD DIOXIDE
Proper Shipping Name (ADN) :	LEAD DIOXIDE
Proper Shipping Name (RID) :	LEAD DIOXIDE
Transport document description (ADR) :	UN 1872, LEAD DIOXIDE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1872, LEAD DIOXIDE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1872, LEAD DIOXIDE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1872, LEAD DIOXIDE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1872, LEAD DIOXIDE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
IMDG
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
IATA
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
ADN
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
RID
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OT2 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP2 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Tank special provisions (ADR) : TU3 Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24, CV28 Hazard identification number (Kemler No.) : 56 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1X
- Transport by sea
Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-Q Stowage category (IMDG) : A MFAG-No : 141
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y546 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 559 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 563 CAO max net quantity (IATA) : 100kg ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : OT2 Special provisions (ADN) : 802 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : OT2 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP2 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Special provisions for RID tanks (RID) : TU3 Transport category (RID) : 3 Special provisions for carriage – Loading and unloading (RID) : CW24, CW28 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 56
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions LEAD DIOXIDE AR is not on the REACH Candidate List LEAD DIOXIDE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Ox. Sol. 2 Oxidising Solids, Category 2 Repr. 1A Reproductive toxicity, Category 1A STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H272 May intensify fire; oxidiser H302 Harmful if swallowed H332 Harmful if inhaled H360Df May damage the unborn child. Suspected of damaging fertility H372 Causes damage to organs through prolonged or repeated exposure H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects O Oxidising