N-(2-AMINOETHYL) ETHANOLAMINE For Synthesis |
| Synonyms : 2-(2-Aminoethylamino)ethanol, N-(2-Hydroxyethyl)ethylenediamine |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | N-(2-AMINOETHYL) ETHANOLAMINE (for synthesis) | ||
| Catalogue No. : | AL0271 | Product form : | Substance |
| CAS Number : | 111-41-1 | EC Number : | 203-867-5 |
| Grade : | EC Index Number : | 603-194-00-0 | |
| Chemical Formula : | HSN Code : | 29221990 | |
| Synonyms : | 2-(2-Aminoethylamino)ethanol | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Skin corrosion/irritation, Category 1B H314 Skin sensitisation, Category 1 H317 Reproductive toxicity, Category 1A H360 Full text of hazard classes and H-statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Repr.Cat.2; R61 Repr.Cat.3; R62 C; R34 R43 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS07
 GHS08
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H360 - May damage fertility or the unborn child. |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a doctor. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | N-(2-AMINOETHYL) ETHANOLAMINE FOR SYNTHESIS | ||
| CAS No. : | 111-41-1 | ||
| EC Index No. : | 603-194-00-0 | ||
| EC No. : | 203-867-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. Get medical advice/attention. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Provide good ventilation in process area to prevent formation of vapour. Do not breathe vapours. Obtain special instructions before use. Avoid contact with skin and eyes. |
| Hygiene measures : | Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid Colour |
| Colour : | Clear Colorless. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | No data available |
| Freezing point : | No data available |
| Boiling point : | 238 - 240 °C |
| Flash point : | 144 °C |
| Auto-ignition temperature : | 368 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 0.013 mbar at 20°C |
| Relative vapour density at 20°C : | 3.59 |
| Density : | 1.03 g/cm3 |
| Solubility : | Water: Slightly Soluble |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Overheating. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 2735 |
| UN-No. (IMDG) : | 2735 |
| UN-No. (IATA) : | 2735 |
| UN-No. (ADN) : | 2735 |
| UN-No. (RID) : | 2735 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (IMDG) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (IATA) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (ADN) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (RID) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Transport document description (ADR) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (IMDG) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (IATA) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (ADN) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (RID) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
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| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : C7 Special provisions (ADR) : 274 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T11 Portable tank and bulk container special provisions (ADR) : TP1, TP27 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X APP code : B |
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| - Transport by sea | |
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Special provisions (IMDG) : 274 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T11 Tank special provisions (IMDG) : TP1, TP27 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Segregation (IMDG) : SG35 Properties and observations (IMDG) : Colourless to yellowish liquids or solutions with a pungent odour. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. Reacts violently with acids. Cause burns to skin, eyes and mucous membranes. MFAG-No : 153 |
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| - Air transport | |
| No data available | |
| - Inland waterway transport | |
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Classification code (ADN) : C7 Special provisions (ADN) : 274 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : C7 Special provisions (RID) : 274 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T11 Portable tank and bulk container special provisions (RID) : TP1, TP27 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions N-(2-AMINOETHYL) ETHANOLAMINE FOR SYNTHESIS is not on the REACH Candidate List N-(2-AMINOETHYL) ETHANOLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : N-(2-AMINOETHYL) ETHANOLAMINE FOR SYNTHESIS is listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : N-(2-AMINOETHYL) ETHANOLAMINE FOR SYNTHESIS is listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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