3-AMINO-1-PROPANOL For Synthesis

3-AMINO-1-PROPANOL For Synthesis

Synonyms : 3-Aminopropyl alcohol; Propanolamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : 3-AMINO-1-PROPANOL 99% For Synthesis
Catalogue No. : AL0293 Product form : Substance
CAS Number : 156-87-6 EC Number : 205-864-4
Grade : EC Index Number :
Chemical Formula : HSN Code : 29221990
Synonyms : 3-Aminopropyl alcohol; Propanolamine
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation,
Category 1B
H314
Acute toxicity (oral),
Category 4
H302
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R22
C; R34
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS05GHS05 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protection, face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a doctor
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 3-AMINO-1-PROPANOL 99% For Synthesis
CAS No. : 156-87-6
EC No. : 205-864-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated clothing before reuse. Get
medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Obtain emergency medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Harmful in contact with skin. Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Colorless.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 10 - 12 °C
Freezing point : No data available
Boiling point : 184 - 187 °C
Flash point : 101 °C
Auto-ignition temperature : 385 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 0.4 hPa at 20°C
Relative vapour density at 20°C : No data available
Density : 0.987 g/cm3
Solubility : Water: Soluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2735
UN-No. (IMDG) : 2735
UN-No. (IATA) : 2735
UN-No. (ADN) : 2735
UN-No. (RID) : 2735
14.2. UN proper shipping name
Proper Shipping Name (ADR) : AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE,
N.O.S.
Proper Shipping Name (IMDG) : AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE,
N.O.S.
Proper Shipping Name (IATA) : AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE,
N.O.S.
Proper Shipping Name (ADN) : AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE,
N.O.S.
Proper Shipping Name (RID) : AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE,
N.O.S.
Transport document description (ADR) : UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II
Transport document description (IMDG) : UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II
Transport document description (IATA) : UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II
Transport document description (ADN) : UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II
Transport document description (RID) : UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8
Danger labels : 8
IMDG
Transport hazard class(es) : 8
Danger labels : 8
IATA
Transport hazard class(es) : 8
Danger labels : 8
ADN
Transport hazard class(es) : 8
Danger labels : 8
RID
Transport hazard class(es) : 8
Danger labels : 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C7
Special provision (ADR) : 274
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T11
Portable tank and bulk container special
provisions (ADR)
: TP1, TP27
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
APP code : B
- Transport by sea
Special provision (IMDG) : 274
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T11
Tank special provisions (IMDG) : TP1, TP27
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A
Segregation (IMDG) : SG35
MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
Special provision (IATA) : A3
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C7
Special provisions (ADN) : 274
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C7
Special provision (RID) : 274
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T11
Portable tank and bulk container special
provisions (RID)
: TP1, TP27
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
3-AMINO-1-PROPANOL 99% For Synthesis is not on the REACH Candidate List
3-AMINO-1-PROPANOL 99% For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to
VwVwS, Annex 2; WGK No 1672)
12
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
R22 Harmful if swallowed
R34 Causes burns
C Corrosive
Xn Harmful