tert-AMYL ALCOHOL AR & HPLC |
| Synonyms : 2-Methyl-2-butanol, tert-Pentyl alcohol |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | tert-AMYL ALCOHOL AR & HPLC (2-methyl-2-butanol) | ||
| Catalogue No. : | AL0423 | Product form : | Substance |
| CAS Number : | 75-85-4 | EC Number : | 200-908-9 |
| Grade : | EC Index Number : | 603-007-00-2 | |
| Chemical Formula : | HSN Code : | 29051990 | |
| Synonyms : | 2-Methyl-2-butanol, tert-Pentyl alcohol | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Flammable liquids, Category 2 H225 Acute toxicity (inhal.), Category 4 H332 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of hazard classes and H-statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| F; R11 Xn; R20 Xi; R37/38 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS07
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H225 - Highly flammable liquid and vapour. H315 - Causes skin irritation. H332 - Harmful if inhaled. H335 - May cause respiratory irritation. |
| Precautionary statements (CLP) : | P210 - Keep away from heat, open flames. No smoking. P261 - Avoid breathing vapours, dust, fume, gas. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | tert-AMYL ALCOHOL AR | ||
| CAS No. : | 75-85-4 | ||
| EC Index No. : | 603-007-00-2 | ||
| EC No. : | 200-908-9 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Specific measures (see ... on this label). Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see ... on this label). |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. |
| First-aid measures after ingestion : | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this label). |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : Suspected of causing genetic defects. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | No additional information available |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | Highly flammable liquid and vapour. |
| Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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| General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
| Precautions for safe handling : | Avoid contact with skin and eyes. Use only non-sparking tools. Keep away from sources of ignition - No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapours. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. |
| Storage conditions : | Keep in fireproof place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid Colour |
| Colour : | Clear Colorless. |
| Odour : | camphor odor. |
| Odour threshold : | No data available |
| pH value : | 6 at 118 g/l at 20 °C |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -12 °C |
| Freezing point : | No data available |
| Boiling point : | 102 °C |
| Flash point : | 20 °C |
| Auto-ignition temperature : | 437 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | Flammable Highly flammable liquid and vapour. |
| Vapour pressure : | 16 hPa |
| Relative vapour density at 20°C : | 3 |
| Relative density : | No data available Density : 0.81 g/cm3 |
| Density : | 0.81 g/cm3 Relative gas density : 3.04 |
| Relative gas density : | 3.04 |
| Solubility : | No data available |
| Log Pow : | 0.77 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.012 - 0.09 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| May release flammable gases. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Inhalation: Harmful if inhaled. |
| Skin corrosion/irritation : | Causes skin irritation. pH: 6 at 118 g/l at 20 °C |
| Serious eye damage/irritation : | Not classified pH: 6 at 118 g/l at 20 °C |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | May cause respiratory irritation. |
| STOT-repeated exposure : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | tert-AMYL ALCOHOL AR (75-85-4) Log Pow 0.77 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1105 |
| UN-No. (IMDG) : | 1105 |
| UN-No. (IATA) : | 1105 |
| UN-No. (ADN) : | 1105 |
| UN-No. (RID) : | 1105 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | PENTANOLS |
| Proper Shipping Name (IMDG) : | PENTANOLS |
| Proper Shipping Name (IATA) : | PENTANOLS |
| Proper Shipping Name (ADN) : | PENTANOLS |
| Proper Shipping Name (RID) : | PENTANOLS |
| Transport document description (ADR) : | UN 1105, PENTANOLS, 3, II |
| Transport document description (IMDG) : | UN 1105, PENTANOLS, 3, II |
| Transport document description (IATA) : | UN 1105, PENTANOLS, 3, II |
| Transport document description (ADN) : | UN 1105, PENTANOLS, 3, II |
| Transport document description (RID) : | UN 1105, PENTANOLS, 3, II |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3 
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| IMDG | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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| IATA | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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| ADN | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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| RID | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : F1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1, TP29 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3YE |
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| - Transport by sea | |
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Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1, TP29 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : B Properties and observations (IMDG) : Colourless liquids with a strong odour. Immiscible with water. tertiary-AMYL ALCOHOL: flashpoint 19°C to 21°C c.c. MFAG-No : 129 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provisions (IATA) : A3 ERG code (IATA) : 3L |
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| - Inland waterway transport | |
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Classification code (ADN) : F1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1 |
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| - Rail transport | |
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Classification code (RID) : F1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1, TP29 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions tert-AMYL ALCOHOL AR is not on the REACH Candidate List tert-AMYL ALCOHOL AR is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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