LEAD MONOXIDE AR/ACS

LEAD MONOXIDE AR/ACS

Synonyms : Litharge

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : LEAD MONOXIDE AR
Catalogue No. : AL2708 Product form : Substance
CAS Number : 1317-36-8 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28241010
Synonyms : Litharge
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial. For professional use only.
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral),
Category 4
H302
Acute toxicity (inhal.),
Category 4
H332
Reproductive toxicity,
Category 1A
H360Df
Specific target organ
toxicity Repeated
exposure, Category 2
H373
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.1; R61
Repr.Cat.3; R62
Xn; R20/22
N; R50/53
R33
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS07GHS07 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H302+H332 - Harmful if swallowed or if inhaled
H360Df - May damage the unborn child. Suspected of damaging fertility
H373 - May cause damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P201 - Obtain special instructions before use
P273 - Avoid release to the environment
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P501 - Dispose of contents/container to {0|message= local/regional/national/international regulations>|default=hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation|filter=(_)?DISPOSAL_.+}
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : LEAD MONOXIDE AR
CAS No. : 1317-36-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical
advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : May damage the unborn child. Suspected of damaging fertility. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/injuries after inhalation : Harmful if inhaled.
Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
No additional information available
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : Yellow powder.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 8860 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 10 mm Hg at 10850C
Relative vapour density at 20°C : No data available
Density : 9.53 g/cm3
Solubility : Water: Insoluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed. Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : May damage the unborn child. Suspected of damaging fertility.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Additional information
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : LEAD MONOXIDE AR (1317-36-8) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
LEAD MONOXIDE AR (1317-36-8)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2291
UN-No. (IMDG) : 2291
UN-No. (IATA) : 2291
UN-No. (ADN) : 2291
UN-No. (RID) : 2291
14.2. UN proper shipping name
Proper Shipping Name (ADR) : LEAD COMPOUND, SOLUBLE, N.O.S.
Proper Shipping Name (IMDG) : LEAD COMPOUND, SOLUBLE, N.O.S.
Proper Shipping Name (IATA) : LEAD COMPOUND, SOLUBLE, N.O.S.
Proper Shipping Name (ADN) : LEAD COMPOUND, SOLUBLE, N.O.S.
Proper Shipping Name (RID) : LEAD COMPOUND, SOLUBLE, N.O.S.
Transport document description (ADR) : UN 2291, LEAD COMPOUND, SOLUBLE, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2291, LEAD COMPOUND, SOLUBLE, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 2291, LEAD COMPOUND, SOLUBLE, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2291, LEAD COMPOUND, SOLUBLE, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2291, LEAD COMPOUND, SOLUBLE, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T5
Special provision (ADR) : 199, 274, 535
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAH, L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2Z
- Transport by sea
Special provision (IMDG) : 199, 274
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
MFAG-No : 151
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y645
PCA limited quantity max net quantity
(IATA)
: 10kg
PCA packing instructions (IATA) : 670
PCA max net quantity (IATA) : 100kg
CAO packing instructions (IATA) : 677
CAO max net quantity (IATA) : 200kg
Special provision (IATA) : A92
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T5
Special provisions (ADN) : 199, 274, 535, 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T5
Special provision (RID) : 199, 274, 535
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAH, L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Bulk
(RID)
: VC1, VC2, AP7
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Lead monoxide (lead oxide) is on the REACH Candidate List
LEAD MONOXIDE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK
No 3649)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Repr. 1A Reproductive toxicity, Category 1A
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H302 Harmful if swallowed
H332 Harmful if inhaled
H360Df May damage the unborn child. Suspected of damaging fertility
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
R20/22 Harmful by inhalation and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R61 May cause harm to the unborn child
R62 Possible risk of impaired fertility
N Dangerous for the environment
Xn Harmful