LEAD NITRATE AR/ACS

LEAD NITRATE AR/ACS

Synonyms : Lead (II) nitrate; Lead dinitrate

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : LEAD NITRATE AR (lead (II) nitrate)
Catalogue No. : AL2711 Product form : Substance
CAS Number : 10099-74-8 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28342990
Synonyms : Lead (II) nitrate; Lead dinitrate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids,
Category 2
H272
Acute toxicity (oral),
Category 4
H302
Acute toxicity (inhal.),
Category 4
H332
Reproductive toxicity,
Category 1A
H360
Specific target organ
toxicity Repeated
exposure, Category 2
H373
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.1; R61
Repr.Cat.3; R62
O; R8
Xn; R20/22
Xi; R41
N; R50/53
R33
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS03GHS03 GHS07GHS07 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H272 - May intensify fire; oxidiser
H302+H332 - Harmful if swallowed or if inhaled
H360 - May damage fertility or the unborn child
H373 - May cause damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P201 - Obtain special instructions before use
P220 - Keep/Store away from clothing/¦/combustible materials
P273 - Avoid release to the environment
P308+P313 - IF exposed or concerned: Get medical advice/attention
P501 - Dispose of contents/container to ...
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : LEAD NITRATE AR/ACS
CAS No. : 10099-74-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical
advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : May damage the unborn child. Suspected of damaging fertility. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/injuries after inhalation : Harmful if inhaled.
Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard : Heating may cause a fire or explosion.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : White crystalline.
Odour : odourless.
Odour threshold : No data available
pH value : 3 - 4
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 205 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : 11
Density : 4.53 g/cm3
Solubility : Water: 50 (gm in 100 gm of water)
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : The substance or mixture is classified as oxidizin
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
May intensify fire; oxidiser.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed. Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Not classified
pH: 3 - 4
Serious eye damage/irritation : Not classified
pH: 3 - 4
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : May damage fertility or the unborn child.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Additional information
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
LEAD NITRATE AR/ACS (10099-74-8)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1469
UN-No. (IMDG) : 1469
UN-No. (IATA) : 1469
UN-No. (ADN) : 1469
UN-No. (RID) : 1469
14.2. UN proper shipping name
Proper Shipping Name (ADR) : LEAD NITRATE
Proper Shipping Name (IMDG) : LEAD NITRATE
Proper Shipping Name (IATA) : LEAD NITRATE
Proper Shipping Name (ADN) : LEAD NITRATE
Proper Shipping Name (RID) : LEAD NITRATE
Transport document description (ADR) : UN 1469, LEAD NITRATE, 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 1469, LEAD NITRATE, 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 1469, LEAD NITRATE, 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1469, LEAD NITRATE, 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1469, LEAD NITRATE, 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
IMDG
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
IATA
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
ADN
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
RID
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OT2
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP2
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV24, CV28
Hazard identification number (Kemler No.) : 56
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 1Y
- Transport by sea
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3, BK2
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : A
MFAG-No : 141
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y543
PCA limited quantity max net quantity
(IATA)
: 1kg
PCA packing instructions (IATA) : 558
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 562
CAO max net quantity (IATA) : 25kg
ERG code (IATA) : 5P
- Inland waterway transport
Classification code (ADN) : OT2
Special provisions (ADN) : 802
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : OT2
Limited quantities (RID) : 1kg
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP2
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W11
Special provisions for carriage – Loading
and unloading (RID)
: CW24, CW28
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 56
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Lead dinitrate is on the REACH Candidate List
LEAD NITRATE AR/ACS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK
No 313)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Ox. Sol. 2 Oxidising Solids, Category 2
Repr. 1A Reproductive toxicity, Category 1A
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H272 May intensify fire; oxidiser
H302 Harmful if swallowed
H332 Harmful if inhaled
H360 May damage fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
R20/22 Harmful by inhalation and if swallowed
R33 Danger of cumulative effects
R41 Risk of serious damage to eyes
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R61 May cause harm to the unborn child
R62 Possible risk of impaired fertility
R8 Contact with combustible material may cause fire
N Dangerous for the environment