SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	CROTONALDEHYDE (for synthesis)
Catalogue No. :	AL1562	Product form :	Substance
CAS Number :	123-73-9	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29121910
Synonyms :	2-Butenal
Chemical Structure :
No additional information available :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	Laboratory chemicals
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 2 H330 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 1 H318 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Muta.Cat.3; R68 F; R11 T+; R26 T; R24/25 Xn; R48/22 Xi; R41 Xi; R37/38 N; R50 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS06 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour. H301+H311 - Toxic if swallowed or in contact with skin H315 - Causes skin irritation. H318 - Causes serious eye damage. H330 - Fatal if inhaled. H335 - May cause respiratory irritation. H373 - May cause damage to organs through prolonged or repeated exposure. H400 - Very toxic to aquatic life.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 - Do not breathe vapours, spray, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P201 - Obtain special instructions before use. P370+P378 - In case of fire: Use media other than water to extinguish. P310 - Immediately call a POISON CENTER or doctor.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		CROTONALDEHYDE FOR SYNTHESIS
CAS No. :		123-73-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Wash with plenty of water/…. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : May cause damage to organs. Causes damage to organs. Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Toxic in contact with skin. Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	Avoid contact with skin and eyes. Use only non-sparking tools. Keep away from sources of ignition - No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapours.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Where exposure through inhalation may occur from use, respiratory protection equipment is recommended

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	70.09 g/mol
Colour :	Pale yellow.
Odour :	Pungent.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-76 °C
Freezing point :	No data available
Boiling point :	104 °C
Flash point :	9 °C
Auto-ignition temperature :	160 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Highly flammable liquid and vapour.
Vapour pressure :	32 mm Hg at 20 °C
Relative vapour density at 20°C :	2.41
Density :	0.846 g/cm3
Solubility :	Water: Soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.025 - 0.195 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. Inhalation: Fatal if inhaled.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1143
UN-No. (IMDG) :	1143
UN-No. (IATA) :	1143
UN-No. (ADN) :	1143
UN-No. (RID) :	1143
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CROTONALDEHYDE
Proper Shipping Name (IMDG) :	CROTONALDEHYDE
Proper Shipping Name (IATA) :	CROTONALDEHYDE
Proper Shipping Name (ADN) :	CROTONALDEHYDE
Proper Shipping Name (RID) :	CROTONALDEHYDE
Transport document description (ADR) :	UN 1143, CROTONALDEHYDE, 6.1 (3), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1143, CROTONALDEHYDE, 6.1 (3), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1143, CROTONALDEHYDE, 6.1 (3), I ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1143, CROTONALDEHYDE, 6.1 (3), I ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1143, CROTONALDEHYDE, 6.1 (3), I ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IMDG
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IATA
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
ADN
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
RID
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1 Special provisions (ADR) : 324, 354, 386 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P602 Mixed packing provisions (ADR) : MP8, MP17 Portable tank and bulk container instructions (ADR) : T20 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE19, TE21 Vehicle for tank carriage : FL Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV1, CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S4, S9, S14 Hazard identification number (Kemler No.) : 663 Orange plates : Tunnel restriction code (ADR) : C/D EAC code : •2WE APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 324, 354, 386 Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P602 Tank instructions (IMDG) : T20 Tank special provisions (IMDG) : TP2, TP13, TP35 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : D Stowage and handling (IMDG) : SW1, SW2 Flash point (IMDG) : 13°C c.c. Properties and observations (IMDG) : Colourless, mobile liquid with a pungent odour. Turns to pale yellow in contact with light and air. Miscible with water. Flashpoint: 13°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause lung damage. MFAG-No : 131P
- Air transport
PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : Forbidden CAO max net quantity (IATA) : Forbidden Special provisions (IATA) : A2 ERG code (IATA) : 6Fi
- Inland waterway transport
Classification code (ADN) : TF1 Special provisions (ADN) : 324, 354, 386, 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TF1 Special provisions (RID) : 324, 354, 386 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P602 Mixed packing provisions (RID) : MP8, MP17 Portable tank and bulk container instructions (RID) : T20 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Hazard identification number (RID) : 663
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions CROTONALDEHYDE FOR SYNTHESIS is not on the REACH Candidate List CROTONALDEHYDE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 239) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour. H301 Toxic if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. R11 Highly flammable R24/25 Toxic in contact with skin and if swallowed R26 Very toxic by inhalation R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed R50 Very toxic to aquatic organisms R68 Possible risk of irreversible effects F Highly flammable N Dangerous for the environment T Toxic T+ Very toxic Xi Irritant Xn Harmful