SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	p-NITRO BENZALDEHYDE (for synthesis)
Catalogue No. :	AL3277	Product form :	Substance
CAS Number :	555-16-8	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29130090
Synonyms :	m-Nitrobenzaldehyde
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xi; R36 R43 R52/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		4–NITROBENZALDEHYDE
CAS No. :		555-16-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause an allergic skin reaction. Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Avoid contact with skin and eyes.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Wash hands, forearms and face thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	151.1 g/mol
Colour :	Yellow crystalline.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	103 - 106
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	Water: Insoluble in water
Log Pow :	0.767
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. High temperature. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	4–NITROBENZALDEHYDE AR (555-16-8) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	4–NITROBENZALDEHYDE AR (555-16-8) Log Pow 0.767
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	Not applicable
UN-No. (IMDG) :	Not applicable
UN-No. (IATA) :	Not applicable
UN-No. (ADN) :	Not applicable
UN-No. (RID) :	Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	Not applicable
Proper Shipping Name (IMDG) :	Not applicable
Proper Shipping Name (IATA) :	Not applicable
Proper Shipping Name (ADN) :	Not applicable
Proper Shipping Name (RID) :	Not applicable
Transport document description (ADR) :	Not applicable
Transport document description (IMDG) :	Not applicable
Transport document description (IATA) :	Not applicable
Transport document description (ADN) :	Not applicable
Transport document description (RID) :	Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	Not applicable
IMDG
Transport hazard class(es) :	Not applicable
IATA
Transport hazard class(es) :	Not applicable
ADN
Transport hazard class(es) :	Not applicable
RID
Transport hazard class(es) :	Not applicable
14.4. Packing group
Packing group (ADR) :	Not applicable
Packing group (IMDG) :	Not applicable
Packing group (IATA) :	Not applicable
Packing group (ADN) :	Not applicable
Packing group (RID) :	Not applicable
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 4–NITROBENZALDEHYDE AR is not on the REACH Candidate List 4–NITROBENZALDEHYDE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. R36 Irritating to eyes R43 May cause sensitisation by skin contact R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Xi Irritant