SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	iso-PROPYL BROMIDE (for synthesis)
Catalogue No. :	AL3841	Product form :	Substance
CAS Number :	75-26-3	EC Number :	200-855-1
Grade :		EC Index Number :	602-085-00-5
Chemical Formula :		HSN Code :	29033990
Synonyms :	iso-Propyl bromide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhalation:gas) Category 3 H331 Skin corrosion/irritation, Category 1B H314 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11 Xn; R20/21/22 C; R34 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS06
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour H302 - Harmful if swallowed H311+H331 - Toxic in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP) :	P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		n-PROPYLAMINE FOR SYNTHESIS
CAS No. :		75-26-3
EC Index No. :		602-085-00-5
EC No. :		200-855-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact :	Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Immediately call a POISON CENTER or doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and water. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : Toxic if inhaled. Symptoms/injuries after skin contact : Toxic in contact with skin. Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :
Unsuitable extinguishing media :
5.2 Special hazards arising from the substance or mixture
Special procedures :	Fire hazard : Highly flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment. Comply with applicable regulations.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	ammonical odour.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-83 °C
Freezing point :	No data available
Boiling point :	48.5 °C
Flash point :	-37.26 °C Critical temperature : 223.8 °C
Auto-ignition temperature :	317 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Highly flammable liquid and vapour
Vapour pressure :	245 mm Hg (at 20°C)
Relative vapour density at 20°C :	2.04
Density :	0.719 g/cm3
Solubility :	Water: Very slightly soluble in cold water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.02 - 0.104 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1277
UN-No. (IMDG) :	1277
UN-No. (IATA) :	1277
UN-No. (ADN) :	1277
UN-No. (RID) :	1277
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	PROPYLAMINE
Proper Shipping Name (IMDG) :	PROPYLAMINE
Proper Shipping Name (IATA) :	PROPYLAMINE
Proper Shipping Name (ADN) :	PROPYLAMINE
Proper Shipping Name (RID) :	PROPYLAMINE
Transport document description (ADR) :	UN 1277, PROPYLAMINE, 3 (8), II
Transport document description (IMDG) :	UN 1277, PROPYLAMINE, 3 (8), II
Transport document description (IATA) :	UN 1277, PROPYLAMINE, 3 (8), II
Transport document description (ADN) :	UN 1277, PROPYLAMINE, 3 (8), II
Transport document description (RID) :	UN 1277, PROPYLAMINE, 3 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3 (8)
Danger labels :	3, 8
IMDG
Transport hazard class(es) :	3 (8)
Danger labels :	3, 8
IATA
Transport hazard class(es) :	3 (8)
Danger labels :	3, 8
ADN
Transport hazard class(es) :	3 (8)
Danger labels :	3, 8
RID
Transport hazard class(es) :	3 (8)
Danger labels :	3, 8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FC Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : L4BH Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 338 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2WE APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : E Stowage and handling (IMDG) : SW2 Flash point (IMDG) : below -18°C c.c. MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y340 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 352 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 363 CAO max net quantity (IATA) : 5L ERG code (IATA) : 3CH
- Inland waterway transport
Classification code (ADN) : FC Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : FC Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : L4BH Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 338
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions n-PROPYLAMINE FOR SYNTHESIS is not on the REACH Candidate List n-PROPYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 5870) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Flam. Liq. 2 Flammable liquids, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B H225 Highly flammable liquid and vapour H302 Harmful if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H331 Toxic if inhaled R11 Highly flammable R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R34 Causes burns C Corrosive F Highly flammable Xn Harmful