SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	1, 2-DIBROMOETHANE (for synthesis)
Catalogue No. :	AL1677	Product form :	Substance
CAS Number :	106-93-4	EC Number :	203-444-5
Grade :		EC Index Number :	602-010-00-6
Chemical Formula :	C2H4Br2	HSN Code :	29033100
Synonyms :	Ethylene dibromide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Carcinogenicity, Category 1B H350 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, H315 Category 2 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45 T; R23/24/25 Xi; R36/37/38 N; R51/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS06 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H350 - May cause cancer. H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P201 - Obtain special instructions before use. P261 - Avoid breathing vapours, spray, dust, fume, gas. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		1,2-DIBROMOETHANE FOR SYNTHESIS
CAS No. :		106-93-4
EC Index No. :		602-010-00-6
EC No. :		203-444-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Wash with plenty of water/…. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Obtain emergency medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : May cause cancer. Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Toxic in contact with skin. Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Obtain special instructions before use. Avoid contact with skin and eyes. Do not breathe vapours. Use only outdoors or in a well-ventilated area. Take precautionary measures against static discharge. Provide good ventilation in process area to prevent
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	187.89 g/mol
Colour :	Clear Colorless.
Odour :	chloroform like.
Odour threshold :	10 ppm
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	8 - 11 °C
Freezing point :	No data available
Boiling point :	131 - 132 °C
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	11 mm Hg (at 20°C)
Relative vapour density at 20°C :	6.48
Density :	2.18 g/cm3
Solubility :	Water: Very slightly soluble in cold water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Overheating. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	May cause cancer.
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	1,2-DIBROMOETHANE FOR SYNTHESIS (106-93-4) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1605
UN-No. (IMDG) :	1605
UN-No. (IATA) :	1605
UN-No. (ADN) :	1605
UN-No. (RID) :	1605
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ETHYLENE DIBROMIDE
Proper Shipping Name (IMDG) :	ETHYLENE DIBROMIDE
Proper Shipping Name (IATA) :	ETHYLENE DIBROMIDE
Proper Shipping Name (ADN) :	ETHYLENE DIBROMIDE
Proper Shipping Name (RID) :	ETHYLENE DIBROMIDE
Transport document description (ADR) :	UN 1605, ETHYLENE DIBROMIDE, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1605, ETHYLENE DIBROMIDE, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1605, ETHYLENE DIBROMIDE, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1605, ETHYLENE DIBROMIDE, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1605, ETHYLENE DIBROMIDE, 6.1, I ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1
Danger labels :	6.1
IMDG
Transport hazard class(es) :	6.1
Danger labels :	6.1
IATA
Transport hazard class(es) :	6.1
Danger labels :	6.1
ADN
Transport hazard class(es) :	6.1
Danger labels :	6.1
RID
Transport hazard class(es) :	6.1
Danger labels :	6.1
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T1 Special provisions (ADR) : 354 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P602 Mixed packing provisions (ADR) : MP8, MP17 Portable tank and bulk container instructions (ADR) : T20 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE19, TE21 Vehicle for tank carriage : AT Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV1, CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S14 Hazard identification number (Kemler No.) : 66 Orange plates : Tunnel restriction code (ADR) : C/D EAC code : 2X APP code : B
- Transport by sea
Special provisions (IMDG) : 354 Packing instructions (IMDG) : P602 Tank instructions (IMDG) : T20 Tank special provisions (IMDG) : TP2, TP13, TP37 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2 Properties and observations (IMDG) : Colourless, volatile liquid. Highly toxic if swallowed, by skin contact or by inhalation. MFAG-No : 154
- Air transport
PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : Forbidden CAO max net quantity (IATA) : Forbidden ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T1 Special provisions (ADN) : 354, 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : T1 Special provisions (RID) : 354 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P602 Mixed packing provisions (RID) : MP8, MP17 Portable tank and bulk container instructions (RID) : T20 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Hazard identification number (RID) : 66
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 1,2-DIBROMOETHANE FOR SYNTHESIS is not on the REACH Candidate List 1,2-DIBROMOETHANE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 241) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : 1,2-DIBROMOETHANE FOR SYNTHESIS is listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Carc. 1B Carcinogenicity, Category 1B Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H301 Toxic if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H335 May cause respiratory irritation. H350 May cause cancer. H411 Toxic to aquatic life with long lasting effects. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R36/37/38 Irritating to eyes, respiratory system and skin R45 May cause cancer R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment T Toxic Xi Irritant