ALLYL CHLORIDE For Synthesis |
| Synonyms : 3-Chloropropylene |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | ALLYL CHLORIDE | ||
| Catalogue No. : | AL0176 | Product form : | Substance |
| CAS Number : | 107-05-1 | EC Number : | 203-457-6 |
| Grade : | EC Index Number : | 602-029-00-X | |
| Chemical Formula : | C3H5Cl | HSN Code : | 29032900 |
| Synonyms : | 3-Chloro-1-propene / Chlorallylene | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Flammable liquids, Category 2 H225 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Carcinogenicity, Category 2 H351 Germ cell mutagenicity, H341 Category 2 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 Muta.Cat.3; R68 F; R11 Xn; R20/21/22 Xn; R48/20 Xi; R36/37/38 N; R50 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS08
 GHS07
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H225 - Highly flammable liquid and vapour. H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H341 - Suspected of causing genetic defects. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. H400 - Very toxic to aquatic life. |
| Precautionary statements (CLP) : | P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P261 - Avoid breathing vapours, dust, fume, gas. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | ALLYL CHLORIDE FOR SYNTHESIS | ||
| CAS No. : | 107-05-1 | ||
| EC Index No. : | 602-029-00-X | ||
| EC No. : | 203-457-6 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| First-aid measures after skin contact : | Get medical advice/attention. Wash skin with plenty of water. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | No additional information available |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | No additional information available |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | Highly flammable liquid and vapour. |
| Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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| General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Very toxic to aquatic life. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
| Precautions for safe handling : | Avoid contact with skin and eyes. Use only non-sparking tools. Obtain special instructions before use. Use personal protective equipment as required. Keep away from sources of ignition - No smoking. Do not breathe vapours. Use only outdoors or in a wel |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. |
| Storage conditions : | Keep in fireproof place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 76.53 g/mol |
| Colour : | Clear Colorless. |
| Odour : | pungent odor. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -135 °C |
| Freezing point : | No data available |
| Boiling point : | 45 °C |
| Flash point : | -29 °C |
| Auto-ignition temperature : | 390 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | Flammable Highly flammable liquid and vapour. |
| Vapour pressure : | 395 mbar |
| Relative vapour density at 20°C : | No data available |
| Density : | 0.94 g/cm3 |
| Solubility : | Water: 0.36 g/100ml (20 °C) |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.032 - 0.112 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Highly flammable liquid and vapour. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| May release flammable gases. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled. Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Suspected of causing genetic defects. |
| Carcinogenicity : | Suspected of causing cancer. |
| STOT-single exposure : | May cause respiratory irritation. |
| STOT-repeated exposure : | May cause damage to organs through prolonged or repeated exposure. |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life. |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1100 |
| UN-No. (IMDG) : | 1100 |
| UN-No. (IATA) : | 1100 |
| UN-No. (ADN) : | 1100 |
| UN-No. (RID) : | 1100 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | ALLYL CHLORIDE |
| Proper Shipping Name (IMDG) : | ALLYL CHLORIDE |
| Proper Shipping Name (IATA) : | ALLYL CHLORIDE |
| Proper Shipping Name (ADN) : | ALLYL CHLORIDE |
| Proper Shipping Name (RID) : | ALLYL CHLORIDE |
| Transport document description (ADR) : | UN 1100, ALLYL CHLORIDE, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 1100, ALLYL CHLORIDE, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 1100, ALLYL CHLORIDE, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 1100, ALLYL CHLORIDE, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 1100, ALLYL CHLORIDE, 3 (6.1), I ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1 
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| IMDG | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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| IATA | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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| ADN | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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| RID | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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14.4. Packing group |
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| Packing group (ADR) : | I |
| Packing group (IMDG) : | I |
| Packing group (IATA) : | I |
| Packing group (ADN) : | I |
| Packing group (RID) : | I |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : FT1 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001 Mixed packing provisions (ADR) : MP7, MP17 Portable tank and bulk container instructions (ADR) : T14 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE21 Vehicle for tank carriage : FL Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S22 Hazard identification number (Kemler No.) : 336 Orange plates : Tunnel restriction code (ADR) : C/E EAC code : 3YE |
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| - Transport by sea | |
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Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P001 Tank instructions (IMDG) : T14 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : E Stowage and handling (IMDG) : SW2 Flash point (IMDG) : -29°C c.c. Properties and observations (IMDG) : Colourless liquid with an unpleasant pungent odour. Flashpoint: -29°C c.c. Explosive limits: 3.3% to 11.1% Boiling point: 44°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 131 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 361 CAO max net quantity (IATA) : 30L ERG code (IATA) : 3P |
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| - Inland waterway transport | |
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Classification code (ADN) : FT1 Special provisions (ADN) : 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2 |
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| - Rail transport | |
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Classification code (RID) : FT1 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P001 Mixed packing provisions (RID) : MP7, MP17 Portable tank and bulk container instructions (RID) : T14 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28 Hazard identification number (RID) : 336 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions ALLYL CHLORIDE FOR SYNTHESIS is not on the REACH Candidate List ALLYL CHLORIDE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 15) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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