MAGNESIUM METAL TURNINGS Extra Pure

MAGNESIUM METAL TURNINGS Extra Pure

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : MAGNESIUM (metal) TURNINGS
Catalogue No. : AL2809 Product form : Substance
CAS Number : 7439-95-4 EC Number : 231-104-6
Grade : EC Index Number : 012-001-00-3
Chemical Formula : HSN Code : 81041100
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Pyorphoric Solids,
Category 1
H250
Substances and Mixtures
which, in contact with
water, emit flammable
gases, Category 1
H260
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R15
F; R17
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02
Signal word (CLP) : Danger
Hazard statements (CLP) : H250 - Catches fire spontaneously if exposed to air
H260 - In contact with water releases flammable gases which may ignite
spontaneously
Precautionary statements (CLP) : P222 - Do not allow contact with air
P223 - Keep away from any possible contact with water, because of violent reaction
and possible flash fire
P231+P232 - Handle under inert gas. Protect from moisture
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P370+P378 - In case of fire: Use ... for extinction
P422 - Store contents under ...
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : MAGNESIUM (METAL) TURNINGS
CAS No. : 7439-95-4
EC Index No. : 012-001-00-3
EC No. : 231-104-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard :
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Do not allow contact with air.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Do not allow water (or moist air) contact with this material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable. Catches fire spontaneously if exposed to air. Keep away from any possible contact with water, because of violent reaction and possible flash fire.
Precautions for safe handling : No naked lights. No smoking. Do not allow contact with air. Protect from moisture. Handle under inert gas.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Store contents under ...
Storage conditions : Store in a dry place. Protect from moisture.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 24.31 g/mol
Colour : silver white.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 648 °C
Freezing point : No data available
Boiling point : 11000 °C
Flash point : No data available
Auto-ignition temperature : 4730 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Catches fire spontaneously if exposed to air,In co
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 1.74 g/cm3
Solubility : Water: Insoluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Catches fire spontaneously if exposed to air. Could react violently or explosively on contact with
10.2 Chemical stability
Catches fire spontaneously if exposed to air.
10.3 Possibility of hazardous reactions
Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which
10.4 Conditions to avoid
Do not allow contact with air. Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1869
UN-No. (IMDG) : 1869
UN-No. (IATA) : 1869
UN-No. (ADN) : 1869
UN-No. (RID) : 1869
14.2. UN proper shipping name
Proper Shipping Name (ADR) : MAGNESIUM
Proper Shipping Name (IMDG) : MAGNESIUM
Proper Shipping Name (IATA) : MAGNESIUM
Proper Shipping Name (ADN) : MAGNESIUM
Proper Shipping Name (RID) : MAGNESIUM
Transport document description (ADR) : UN 1869, MAGNESIUM, 4.1, III
Transport document description (IMDG) : UN 1869, MAGNESIUM, 4.1, III
Transport document description (IATA) : UN 1869, MAGNESIUM, 4.1, III
Transport document description (ADN) : UN 1869, MAGNESIUM, 4.1, III
Transport document description (RID) : UN 1869, MAGNESIUM, 4.1, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 4.1
Danger labels : 4.1
IMDG
Transport hazard class(es) : 4.1
Danger labels : 4.1
IATA
Transport hazard class(es) : 4.1
Danger labels : 4.1
ADN
Transport hazard class(es) : 4.1
Danger labels : 4.1
RID
Transport hazard class(es) : 4.1
Danger labels : 4.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F3
Special provision (ADR) : 59
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP11
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2
Hazard identification number (Kemler No.) : 40
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 1Z
- Transport by sea
Special provision (IMDG) : 59, 920
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-G
EmS-No. (Spillage) : S-G
Stowage category (IMDG) : A
Stowage and handling (IMDG) : H1
Segregation (IMDG) : SG17, SG32, SG35, SG36, SG52, SG25, SG26
MFAG-No : 138
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y443
PCA limited quantity max net quantity
(IATA)
: 10kg
PCA packing instructions (IATA) : 446
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 449
CAO max net quantity (IATA) : 100kg
Special provision (IATA) : A15
ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F3
Special provisions (ADN) : 59
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : F3
Special provision (RID) : 59
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP11
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W1
Special provisions for carriage – Bulk
(RID)
: VC1, VC2
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 40
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
MAGNESIUM (METAL) TURNINGS is not on the REACH Candidate List
MAGNESIUM (METAL) TURNINGS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) nwg, non-hazardous to water (KBwS-Beschluss; WGK
No 1443)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Pyr. Sol. 1 Pyorphoric Solids, Category 1
Water-react. 1 Substances and Mixtures which, in contact with water, emit flammable gases, Category 1
H250 Catches fire spontaneously if exposed to air
H260 In contact with water releases flammable gases which may ignite spontaneously
R15 Contact with water liberates extremely flammable gases
R17 Spontaneously flammable in air
F Highly flammable