SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	SODAMIDE
Catalogue No. :	AL4048	Product form :	Substance
CAS Number :	7782-92-5	EC Number :	231-971-0
Grade :		EC Index Number :
Chemical Formula :	H2NNa	HSN Code :	28539010v
Synonyms :	Sodium amide
Chemical Structure :	H2NNa
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Substances and Mixtures which, in contact with water, emit flammable gases, Category 2 H261 Skin corrosion/irritation, Category 1 H314 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R14/15 C; R34 N; R50 R19 R29 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H261 - In contact with water releases flammable gases H314 - Causes severe skin burns and eye damage H400 - Very toxic to aquatic life
Precautionary statements (CLP) :	P231+P232 - Handle under inert gas. Protect from moisture P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		SODAMIDE Extra Pure
CAS No. :		7782-92-5
EC No. :		231-971-0
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact :	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	In contact with water releases flammable gases. Reactivity in case of fire : Reacts with water (moisture): release of
Explosion hazard :
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	No naked lights. No smoking. Use special care to avoid static electric charges. Remove ignition sources.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment. Do not allow water (or moist air) contact with this material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Large spills: scoop solid spill into closing containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Keep away from any possible contact with water, because of violent reaction and possible flash fire. Hazardous waste due to potential risk of explosion.
Precautions for safe handling :	Protect from moisture. Handle under inert gas. Do not breathe dust/fume/gas/mist/vapours/spray. Keep away from sources of ignition - No smoking. No naked lights. No smoking.
Hygiene measures :	Wash ... thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed.
Storage conditions :	Store in a dry place. Protect from moisture. Store in dry protected location to prevent any moisture contact. Keep in fireproof place. Incompatible products : Oxidizing agent.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Colour
Colour :	Greyish white powder.
Odour :	ammonia like.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	210 °C
Freezing point :	No data available
Boiling point :	400 °C
Flash point :	No data available
Auto-ignition temperature :	4500 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	In contact with water releases flammable gases whi
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	Water: Reacts with water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	May form explosive peroxides.
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours. Reacts violently with water.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
In contact with water releases flammable gases which may ignite spontaneously. Highly reactive mat
10.4 Conditions to avoid
Moisture. Heat. Sparks. Open flame. Direct sunlight. Overheating.
10.5 Incompatible materials
Oxidizing agent.
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours. May form explosive peroxides.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Do not allow water (or moist air) contact with this material. Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1390
UN-No. (IMDG) :	1390
UN-No. (IATA) :	1390
UN-No. (ADN) :	1390
UN-No. (RID) :	1390
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ALKALI METAL AMIDES
Proper Shipping Name (IMDG) :	ALKALI METAL AMIDES
Proper Shipping Name (IATA) :	ALKALI METAL AMIDES
Proper Shipping Name (ADN) :	ALKALI METAL AMIDES
Proper Shipping Name (RID) :	ALKALI METAL AMIDES
Transport document description (ADR) :	UN 1390, ALKALI METAL AMIDES, 4.3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1390, ALKALI METAL AMIDES, 4.3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1390, ALKALI METAL AMIDES, 4.3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1390, ALKALI METAL AMIDES, 4.3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1390, ALKALI METAL AMIDES, 4.3, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	4.3
Danger labels :	4.3
IMDG
Transport hazard class(es) :	4.3
Danger labels :	4.3
IATA
Transport hazard class(es) :	4.3
Danger labels :	4.3
ADN
Transport hazard class(es) :	4.3
Danger labels :	4.3
RID
Transport hazard class(es) :	4.3
Danger labels :	4.3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : W2 Special provision (ADR) : 182, 505 Limited quantities (ADR) : 500g Excepted quantities (ADR) : E2 Packing instructions (ADR) : P410, IBC07 Mixed packing provisions (ADR) : MP14 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Vehicle for tank carriage : AT Transport category (ADR) : 0 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV23 Hazard identification number (Kemler No.) : 423 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 4W
- Transport by sea
Special provision (IMDG) : 182 Limited quantities (IMDG) : 500 g Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P410 Packing provisions (IMDG) : PP31, PP40 IBC packing instructions (IMDG) : IBC07 IBC special provisions (IMDG) : B2 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-G EmS-No. (Spillage) : S-O Stowage category (IMDG) : E Stowage and handling (IMDG) : SW2, H1 Segregation (IMDG) : SG35, SG26 MFAG-No : 139
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y475 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 483 PCA max net quantity (IATA) : 15kg CAO packing instructions (IATA) : 489 CAO max net quantity (IATA) : 50kg Special provision (IATA) : A84 ERG code (IATA) : 4W
- Inland waterway transport
Classification code (ADN) : W2 Special provisions (ADN) : 182, 505 Limited quantities (ADN) : 500 g Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Provisions for handling and stowage of the cargo (ADN) : HA08 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : W2 Special provision (RID) : 182, 505 Limited quantities (RID) : 500g Excepted quantities (RID) : E2 Packing instructions (RID) : P410, IBC07 Mixed packing provisions (RID) : MP14 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Transport category (RID) : 0 Special provisions for carriage – Packages (RID) : W1 Special provisions for carriage – Loading and unloading (RID) : CW23 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 423
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Sodamide is not on the REACH Candidate List Sodamide is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 1280) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Skin Corr. 1 Skin corrosion/irritation, Category 1 Water-react. 2 Substances and Mixtures which, in contact with water, emit flammable gases, Category 2 H261 In contact with water releases flammable gases H314 Causes severe skin burns and eye damage H400 Very toxic to aquatic life R14/15 Reacts violently with water, liberating extremely flammable gases R19 May form explosive peroxides R29 Contact with water liberates toxic gas R34 Causes burns R50 Very toxic to aquatic organisms C Corrosive F Highly flammable N Dangerous for the environment