SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	ETHYLENE DIAMINE
Catalogue No. :	AL2071	Product form :	Substance
CAS Number :	107-15-3	EC Number :	203-468-6
Grade :		EC Index Number :	612-006-00-6
Chemical Formula :		HSN Code :	29212100
Synonyms :	1,2-Diaminoethane
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Skin corrosion/irritation, Category 1B H314 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R21/22 R42 C; R34 R43 R10 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour. H302+H312 - Harmful if swallowed or in contact with skin H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements (CLP) :	P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards :	This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		ETHYLENEDIAMINE For Synthesis
CAS No. :		107-15-3
EC Index No. :		612-006-00-6
EC No. :		203-468-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. Specific measures (see supplemental first aid instruction on this label). Wash with plenty of water/…. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label).
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions :	Keep container tightly closed. Store in original container. Store in a dry place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	In case of inadequate ventilation wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	60.1 g/mol
Colour :	Clear Colorless.
Odour :	amine like.
Odour threshold :	No data available
pH value :	12.2 at 110 g/l at 20 °C
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	8.5 °C
Freezing point :	No data available
Boiling point :	118 °C
Flash point :	38 °C
Auto-ignition temperature :	379 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour.
Vapour pressure :	13 hPa at 20 °C
Relative vapour density at 20°C :	2.07
Density :	0.89 g/cm3
Solubility :	Water: Soluble in water
Log Pow :	2.04
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.027 - 0.16 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Dermal: Harmful in contact with skin.
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 12.2 at 110 g/l at 20 °C
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 12.2 at 110 g/l at 20 °C
Respiratory or skin sensitisation :	May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	ETHYLENEDIAMINE For Synthesis (107-15-3) Log Pow 2.04
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
ETHYLENEDIAMINE For Synthesis (107-15-3) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1604
UN-No. (IMDG) :	1604
UN-No. (IATA) :	1604
UN-No. (ADN) :	1604
UN-No. (RID) :	1604
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ETHYLENEDIAMINE
Proper Shipping Name (IMDG) :	ETHYLENEDIAMINE
Proper Shipping Name (IATA) :	ETHYLENEDIAMINE
Proper Shipping Name (ADN) :	ETHYLENEDIAMINE
Proper Shipping Name (RID) :	ETHYLENEDIAMINE
Transport document description (ADR) :	UN 1604, ETHYLENEDIAMINE, 8 (3), II
Transport document description (IMDG) :	UN 1604, ETHYLENEDIAMINE, 8 (3), II
Transport document description (IATA) :	UN 1604, ETHYLENEDIAMINE, 8 (3), II
Transport document description (ADN) :	UN 1604, ETHYLENEDIAMINE, 8 (3), II
Transport document description (RID) :	UN 1604, ETHYLENEDIAMINE, 8 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IMDG
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IATA
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
ADN
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
RID
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CF1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 83 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2W APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 Segregation (IMDG) : SG35 Flash point (IMDG) : 34°C c.c. MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8F
- Inland waterway transport
Classification code (ADN) : CF1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : CF1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 83
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Ethylenediamine (EDA) is on the REACH Candidate List ETHYLENEDIAMINE For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 103) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Flam. Liq. 3 Flammable liquids, Category 3 Resp. Sens. 1 Respiratory sensitisation, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1 Skin sensitisation, Category 1 H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. R10 Flammable R21/22 Harmful in contact with skin and if swallowed R34 Causes burns R42 May cause sensitization by inhalation R43 May cause sensitisation by skin contact C Corrosive Xn Harmful