SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	HYDRAZINE HYDRATE 80% (for synthesis)
Catalogue No. :	AL2427	Product form :	Substance
CAS Number :	7803-57-8	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	28251020
Synonyms :	Hydrazinium hydroxide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 1B H314 Sensitisation Skin, category 1 H317 Carcinogenicity, Category 1A H350 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.1; R45 T; R23/24/25 C; R34 R43 N; R50/53 R10 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS06 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H350 - May cause cancer H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards :	This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		HYDRAZINE HYDRATE FOR SYNTHESIS
CAS No. :		7803-57-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact :	Remove/Take off immediately all contaminated clothing. Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion :	Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after skin contact : Toxic in contact with skin. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. Chronic symptoms : May cause cancer.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel. Do not breathe gas.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Avoid contact with skin and eyes.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations.
Storage conditions :	Keep container tightly closed. Store in a well-ventilated place. Keep cool.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	ammonia like.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-57 °C
Freezing point :	No data available
Boiling point :	117 °C
Flash point :	96 °C
Auto-ignition temperature :	310 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour
Vapour pressure :	No data available
Relative vapour density at 20°C :	1.1
Density :	1.028 g/cm3
Solubility :	Water: Miscible with water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	0.9 cP
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	3.5 - 99.99 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled.
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	May cause cancer.
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified HYDRAZINE HYDRATE FOR SYNTHESIS (7803-57-8) Viscosity, kinematic 0.87548638 mm²/s
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	HYDRAZINE HYDRATE FOR SYNTHESIS (7803-57-8) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
HYDRAZINE HYDRATE FOR SYNTHESIS (7803-57-8) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2030
UN-No. (IMDG) :	2030
UN-No. (IATA) :	2030
UN-No. (ADN) :	2030
UN-No. (RID) :	2030
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	HYDRAZINE, AQUEOUS SOLUTION
Proper Shipping Name (IMDG) :	HYDRAZINE, AQUEOUS SOLUTION
Proper Shipping Name (IATA) :	HYDRAZINE, AQUEOUS SOLUTION
Proper Shipping Name (ADN) :	HYDRAZINE, AQUEOUS SOLUTION
Proper Shipping Name (RID) :	HYDRAZINE, AQUEOUS SOLUTION
Transport document description (ADR) :	UN 2030, HYDRAZINE, AQUEOUS SOLUTION, 8 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2030, HYDRAZINE, AQUEOUS SOLUTION, 8 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2030, HYDRAZINE, AQUEOUS SOLUTION, 8 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2030, HYDRAZINE, AQUEOUS SOLUTION, 8 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2030, HYDRAZINE, AQUEOUS SOLUTION, 8 (6.1), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
IMDG
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
IATA
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
ADN
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
RID
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CT1 Special provision (ADR) : 530 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Hazard identification number (Kemler No.) : 86 Orange plates : Tunnel restriction code (ADR) : E EAC code : •2X APP code : B
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2 Segregation (IMDG) : SG35 MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L Special provision (IATA) : A1, A36 ERG code (IATA) : 8P
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Hydrazine is on the REACH Candidate List HYDRAZINE HYDRATE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK No 130) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Carc. 1A Carcinogenicity, Category 1A Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1 Sensitisation — Skin, category 1 H226 Flammable liquid and vapour H301 Toxic if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H331 Toxic if inhaled H350 May cause cancer H410 Very toxic to aquatic life with long lasting effects R10 Flammable R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R43 May cause sensitisation by skin contact R45 May cause cancer R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment C Corrosive N Dangerous for the environment T Toxic