DICYLOHEXYLAMINE For Synthesis

DICYLOHEXYLAMINE For Synthesis

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : DICYCLOHEXYLAMINE
Catalogue No. : AL1737 Product form : Substance
CAS Number : 101-83-7 EC Number : 202-980-7
Grade : EC Index Number : 612-066-00-3
Chemical Formula : C12H23N HSN Code : 29213090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral),
Category 4
H302
Skin corrosion/irritation,
Category 1B
H314
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R22
C; R34
N; R50/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS05GHS05 GHS07GHS07 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
P501 - Dispose of contents/container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : DICYCLOHEXYLAMINE FOR SYNTHESIS
CAS No. : 101-83-7
EC Index No. : 612-066-00-3
EC No. : 202-980-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce
vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 181.32 g/mol
Colour : Clear Colorless.
Odour : fishy/amine odor.
Odour threshold : No data available
pH value : 11 at 1 g/l at 20 °C
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 2 °C
Freezing point : No data available
Boiling point : 117 - 120 °C
Flash point : 96 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : 6.27
Density : 0.91 g/cm3
Solubility : Water: Sparingly soluble in water
Log Pow : 0.4
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
High temperature. Heat. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 11 at 1 g/l at 20 °C
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 11 at 1 g/l at 20 °C
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : DICYCLOHEXYLAMINE FOR SYNTHESIS (101-83-7) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : DICYCLOHEXYLAMINE FOR SYNTHESIS (101-83-7) Log Pow 0.4
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2565
UN-No. (IMDG) : 2565
UN-No. (IATA) : 2565
UN-No. (ADN) : 2565
UN-No. (RID) : 2565
14.2. UN proper shipping name
Proper Shipping Name (ADR) : DICYCLOHEXYLAMINE
Proper Shipping Name (IMDG) : DICYCLOHEXYLAMINE
Proper Shipping Name (IATA) : DICYCLOHEXYLAMINE
Proper Shipping Name (ADN) : DICYCLOHEXYLAMINE
Proper Shipping Name (RID) : DICYCLOHEXYLAMINE
Transport document description (ADR) : UN 2565, DICYCLOHEXYLAMINE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2565, DICYCLOHEXYLAMINE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 2565, DICYCLOHEXYLAMINE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2565, DICYCLOHEXYLAMINE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2565, DICYCLOHEXYLAMINE, 8, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8
Danger labels : 8
IMDG
Transport hazard class(es) : 8
Danger labels : 8
IATA
Transport hazard class(es) : 8
Danger labels : 8
ADN
Transport hazard class(es) : 8
Danger labels : 8
RID
Transport hazard class(es) : 8
Danger labels : 8
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C7
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T4
Portable tank and bulk container special
provisions (ADR)
: TP1
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V12
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
- Transport by sea
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A
Properties and observations (IMDG) : Clear, colourless, combustible liquid with a fishy odour which may taint other
cargoes. Immiscible with water. Causes burns to skin, eyes and mucous
membranes.
MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y841
PCA limited quantity max net quantity
(IATA)
: 1L
PCA packing instructions (IATA) : 852
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 856
CAO max net quantity (IATA) : 60L
Special provisions (IATA) : A803
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C7
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C7
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID)
: T4
Portable tank and bulk container special
provisions (RID)
: TP1
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W12
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
DICYCLOHEXYLAMINE FOR SYNTHESIS is not on the REACH Candidate List
DICYCLOHEXYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to
AwSV; ID No. 1226)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.
R22 Harmful if swallowed
R34 Causes burns
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
C Corrosive
N Dangerous for the environment
Xn Harmful