DIISOPROPYLAMINE For Synthesis

DIISOPROPYLAMINE For Synthesis

Synonyms : DIPA

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : DIISOPROPYLAMINE
Catalogue No. : AL1795 Product form : Substance
CAS Number : 108-18-9 EC Number : 203-558-5
Grade : EC Index Number : 612-129-00-5
Chemical Formula : C6H15N HSN Code : 29211190
Synonyms : DIPA
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids,
Category 2
H225
Acute toxicity (oral),
Category 4
H302
Acute toxicity (inhal.),
Category 4
H332
Skin corrosion/irritation,
Category 1B
H314
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11
Xn; R20/22
C; R34
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS05GHS05 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H302+H332 - Harmful if swallowed or if inhaled
H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a doctor.
EUH-statements : EUH071 - Corrosive to the respiratory tract.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : DIISOPROPYLAMINE FOR SYNTHESIS
CAS No. : 108-18-9
EC Index No. : 612-129-00-5
EC No. : 203-558-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Immediately call a POISON
CENTER/doctor. Wash with plenty of water/….
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after inhalation : Corrosive to the respiratory tract.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Avoid contact with skin and eyes. Use only non-sparking tools. Keep away from sources of ignition - No smoking. Do not breathe vapours. Take precautionary measures against static discharge. Provide good ventilation in process area to prevent formation
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions : Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 101.1 g/mol
Colour : Clear Colorless.
Odour : amine-like odor.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -61 °C
Freezing point : No data available
Boiling point : 84 °C
Flash point : -7 °C
Auto-ignition temperature : 316 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable Highly flammable liquid and vapour.
Vapour pressure : 67 hPa at 20 °C
Relative vapour density at 20°C : 3.49
Density : 0.722 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.011 - 0.085 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed. Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
Additional information : Corrosive to the respiratory tract.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1158
UN-No. (IMDG) : 1158
UN-No. (IATA) : 1158
UN-No. (ADN) : 1158
UN-No. (RID) : 1158
14.2. UN proper shipping name
Proper Shipping Name (ADR) : DIISOPROPYLAMINE
Proper Shipping Name (IMDG) : DIISOPROPYLAMINE
Proper Shipping Name (IATA) : DIISOPROPYLAMINE
Proper Shipping Name (ADN) : DIISOPROPYLAMINE
Proper Shipping Name (RID) : DIISOPROPYLAMINE
Transport document description (ADR) : UN 1158, DIISOPROPYLAMINE, 3 (8), II
Transport document description (IMDG) : UN 1158, DIISOPROPYLAMINE, 3 (8), II
Transport document description (IATA) : UN 1158, DIISOPROPYLAMINE, 3 (8), II
Transport document description (ADN) : UN 1158, DIISOPROPYLAMINE, 3 (8), II
Transport document description (RID) : UN 1158, DIISOPROPYLAMINE, 3 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
IMDG
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
IATA
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
ADN
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
RID
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FC
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP1
Tank code (ADR) : L4BH
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Operation
(ADR)
: S2, S20
Hazard identification number (Kemler No.) : 338
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •3WE
APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : B
Flash point (IMDG) : -7°C c.c.
Properties and observations (IMDG) : Colourless, volatile liquid with a fishy odour. Flashpoint: -7°C c.c. Explosive limits:
1.1% to 7.1% Partially miscible with water. Harmful by inhalation. Causes burns to
skin, eyes and mucous membranes.
MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y340
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 352
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 363
CAO max net quantity (IATA) : 5L
ERG code (IATA) : 3CH
- Inland waterway transport
Classification code (ADN) : FC
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : FC
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP1
Tank codes for RID tanks (RID) : L4BH
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE7
Hazard identification number (RID) : 338
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
DIISOPROPYLAMINE FOR SYNTHESIS is not on the REACH Candidate List
DIISOPROPYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to
AwSV; ID No. 614)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be
followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Flam. Liq. 2 Flammable liquids, Category 2
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
EUH071 Corrosive to the respiratory tract.
R11 Highly flammable
R20/22 Harmful by inhalation and if swallowed
R34 Causes burns
C Corrosive
F Highly flammable
Xn Harmful