N-ETHYLANILINE For Synthesis |
| Synonyms : Monoethylaniline |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | ETHYLANILINE (mono) (monoethylaniline) (N-ethylaniline) | ||
| Catalogue No. : | AL2049 | Product form : | Substance |
| CAS Number : | 103-69-5 | EC Number : | 203-135-5 |
| Grade : | EC Index Number : | 612-053-00-2 | |
| Chemical Formula : | C8H11N | HSN Code : | 29214290 |
| Synonyms : | Monoethylaniline | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Specific target organ toxicity Repeated exposure, Category 2 H373 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| T; R23/24/25 R33 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H373 - May cause damage to organs through prolonged or repeated exposure. |
| Precautionary statements (CLP) : | P361 - Take off immediately all contaminated clothing. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P311 - Call a POISON CENTER/doctor |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | N-ETHYLANILINE FOR SYNTHESIS | ||
| CAS No. : | 103-69-5 | ||
| EC Index No. : | 612-053-00-2 | ||
| EC No. : | 203-135-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Get medical advice/attention if you feel unwell. |
| First-aid measures after skin contact : | Take off immediately all contaminated clothing. Wash with plenty of water/…. Wash contaminated clothing before reuse. Get immediate medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER/doctor. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : May cause damage to organs through prolonged or repeated exposure. Symptoms/effects after inhalation : Toxic if inhaled. Symptoms/effects after skin contact : Toxic in contact with skin. Symptoms/effects after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Water spray. Dry powder. Carbon dioxide. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Keep container tightly closed. Keep container closed when not in use. Incompatible products : Strong acids. Strong bases. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 121.18 g/mol |
| Colour : | Yellow to brown. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -63 °C |
| Freezing point : | No data available |
| Boiling point : | 205 °C |
| Flash point : | 85 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 0.3 hPa at 20 °C |
| Relative vapour density at 20°C : | 4.18 |
| Density : | 0.96 g/cm3 |
| Solubility : | No data available |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.016 - 0.095 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Extremely high or low temperatures. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Carbon dioxide. Carbon monoxide. fume. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | May cause damage to organs through prolonged or repeated exposure. Additional information : There are potential chronic health effects to consider |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 2272 |
| UN-No. (IMDG) : | 2272 |
| UN-No. (IATA) : | 2272 |
| UN-No. (ADN) : | 2272 |
| UN-No. (RID) : | 2272 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | N-ETHYLANILINE |
| Proper Shipping Name (IMDG) : | N-ETHYLANILINE |
| Proper Shipping Name (IATA) : | N-ETHYLANILINE |
| Proper Shipping Name (ADN) : | N-ETHYLANILINE |
| Proper Shipping Name (RID) : | N-ETHYLANILINE |
| Transport document description (ADR) : | UN 2272, N-ETHYLANILINE, 6.1, III |
| Transport document description (IMDG) : | UN 2272, N-ETHYLANILINE, 6.1, III |
| Transport document description (IATA) : | UN 2272, N-ETHYLANILINE, 6.1, III |
| Transport document description (ADN) : | UN 2272, N-ETHYLANILINE, 6.1, III |
| Transport document description (RID) : | UN 2272, N-ETHYLANILINE, 6.1, III |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T1 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 3Z |
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| - Transport by sea | |
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Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Segregation (IMDG) : SG17, SG35 Properties and observations (IMDG) : Colourless to yellowish oily liquid. Reacts with acids, evolving highly toxic fumes of aniline and oxides of nitrogen. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 153 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y642 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 655 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 663 CAO max net quantity (IATA) : 220L ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : T1 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions N-ETHYLANILINE FOR SYNTHESIS is not on the REACH Candidate List N-ETHYLANILINE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 252) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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