HYDROXYLAMINE HYDROCHLORIDE For Synthesis

HYDROXYLAMINE HYDROCHLORIDE For Synthesis

Synonyms : Hydroxylammonium Chloride

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : HYDROXYLAMINE HYDROCHLORIDE (for synthesis)
Catalogue No. : AL2502 Product form : Substance
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28251090
Synonyms : Hydroxylammonium Chloride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial. For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal),
Category 4
H312
Acute toxicity (oral),
Category 4
H302
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40
Xn; R21/22
Xn; R48/22
Xi; R36/38
R43
N; R50
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS07GHS07 GHS09GHS09 GHS05GHS05 GHS08GHS08
Signal word (CLP) : Warning
Hazard statements (CLP) : H302+H312 - Harmful if swallowed or in contact with skin
H400 - Very toxic to aquatic life
Precautionary statements (CLP) : P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : HYDROXYLAMINE HYDROCHLORIDE FOR SYNTHESIS Full text of R- and H-phrases: see section 16 3.2. Mixture Not applicable SE
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Immediately call a POISON CENTER or doctor/physician. Specific measures (see ...
on this label). Wash with plenty of soap and water. Wash contaminated clothing
before reuse.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Harmful in contact with skin.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray.
Unsuitable extinguishing media : dry chemical powder. Foam. Carbon dioxide (CO2). Water.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : No additional information available

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : White crystalline.
Odour : odourless.
Odour threshold : No data available
pH value : 2.5 - 3.5
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 155 - 157
Freezing point : No data available
Boiling point : 305.6 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 1.67 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Harmful in contact with skin. Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
pH: 2.5 - 3.5
Serious eye damage/irritation : Not classified
pH: 2.5 - 3.5
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2923
UN-No. (IMDG) : 2923
UN-No. (IATA) : 2923
UN-No. (ADN) : 2923
UN-No. (RID) : 2923
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (IMDG) : CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (IATA) : CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (ADN) : CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (RID) : CORROSIVE SOLID, TOXIC, N.O.S.
Transport document description (ADR) : UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
IMDG
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
IATA
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
ADN
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
RID
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CT2
Special provision (ADR) : 274
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV, L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Hazard identification number (Kemler No.) : 86
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
- Transport by sea
Special provision (IMDG) : 223, 274
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y845
PCA limited quantity max net quantity
(IATA)
: 5kg
PCA packing instructions (IATA) : 860
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 864
CAO max net quantity (IATA) : 100kg
Special provision (IATA) : A3
ERG code (IATA) : 8P
- Inland waterway transport
Classification code (ADN) : CT2
Special provisions (ADN) : 274, 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : CT2
Special provision (RID) : 274
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV, L4BN
Transport category (RID) : 3
Special provisions for carriage – Bulk
(RID)
: VC1, VC2, AP7
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW28
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 86
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
HYDROXYLAMINE HYDROCHLORIDE FOR SYNTHESIS is not on the REACH Candidate List
HYDROXYLAMINE HYDROCHLORIDE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
H302 Harmful if swallowed
H312 Harmful in contact with skin
H400 Very toxic to aquatic life
R21/22 Harmful in contact with skin and if swallowed
R36/38 Irritating to eyes and skin
R40 Limited evidence of a carcinogenic effect
R43 May cause sensitisation by skin contact
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed
R50 Very toxic to aquatic organisms
N Dangerous for the environment
Xi Irritant
Xn Harmful