SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	HYDROXYLAMINE HYDROCHLORIDE AR
Catalogue No. :	AL2503	Product form :	Substance
CAS Number :	5470-11-1	EC Number :
Grade :		EC Index Number :
Chemical Formula :	H4ClNO	HSN Code :	28251090
Synonyms :	Hydroxylammonium chloride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Corrosive to metals, Category 1 H290 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ H373 toxicity Repeated exposure, Category 2 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40 Xn; R21/22 Xn; R48/22 Xi; R36/38 R43 N; R50 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS07 GHS08 GHS09
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H290 - May be corrosive to metals. H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H351 - Suspected of causing cancer (if inhaled, if swallowed, in contact with skin, inhalation). H373 - May cause damage to organs through prolonged or repeated exposure. H400 - Very toxic to aquatic life.
Precautionary statements (CLP) :	P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		HYDROXYLAMINE HYDROCHLORIDE AR/ACS
CAS No. :		5470-11-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Get medical advice/attention.
First-aid measures after skin contact :	Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : May cause damage to organs. Symptoms/effects after inhalation : May cause an allergic skin reaction. Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	69.49 g/mol
Colour :	White crystalline.
Odour :	odourless.
Odour threshold :	No data available
pH value :	2.5 - 3.5
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	155 - 157
Freezing point :	No data available
Boiling point :	305.6 °C
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	1.67 g/cm3
Solubility :	Water: Soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Open flame. Sparks. Extremely high or low temperatures.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Dermal: Harmful in contact with skin.
Skin corrosion/irritation :	Causes skin irritation. pH: 2.5 - 3.5
Serious eye damage/irritation :	Causes serious eye irritation. pH: 2.5 - 3.5
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer (if inhaled, if swallowed, in contact with skin, inhalation).
STOT-single exposure :	Not classified
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2923
UN-No. (IMDG) :	2923
UN-No. (IATA) :	2923
UN-No. (ADN) :	2923
UN-No. (RID) :	2923
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (IMDG) :	CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (IATA) :	CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (ADN) :	CORROSIVE SOLID, TOXIC, N.O.S.
Proper Shipping Name (RID) :	CORROSIVE SOLID, TOXIC, N.O.S.
Transport document description (ADR) :	UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2923, CORROSIVE SOLID, TOXIC, N.O.S., 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
IMDG
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
IATA
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
ADN
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
RID
Transport hazard class(es) :	8 (6.1)
Danger labels :	8, 6.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CT2 Special provisions (ADR) : 274 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV, L4BN Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Hazard identification number (Kemler No.) : 86 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X
- Transport by sea
Special provisions (IMDG) : 223, 274 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : B Stowage and handling (IMDG) : SW2 Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y845 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 860 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 864 CAO max net quantity (IATA) : 100kg Special provisions (IATA) : A3, A803 ERG code (IATA) : 8P
- Inland waterway transport
Classification code (ADN) : CT2 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : CT2 Special provisions (RID) : 274 Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV, L4BN Transport category (RID) : 3 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 86
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions HYDROXYLAMINE HYDROCHLORIDE AR/ACS is not on the REACH Candidate List HYDROXYLAMINE HYDROCHLORIDE AR/ACS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 2937) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Met. Corr. 1 Corrosive to metals, Category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H290 May be corrosive to metals. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. R21/22 Harmful in contact with skin and if swallowed R36/38 Irritating to eyes and skin R40 Limited evidence of a carcinogenic effect R43 May cause sensitisation by skin contact R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed R50 Very toxic to aquatic organisms N Dangerous for the environment Xi Irritant Xn Harmful