SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	HYDROXYLAMINE SULPHATE AR
Catalogue No. :	AL2506	Product form :	Substance
CAS Number :	10039-54-0	EC Number :	233-118-8
Grade :		EC Index Number :	612-123-00-2
Chemical Formula :		HSN Code :	28251040
Synonyms :	Hydroxylammonium Sulphate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only.
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Explosives, Division 1.3 H203 Acute toxicity (dermal), Category 4 H312 Acute toxicity (oral), Category 4 H302 Carcinogenicity, Category 2 H351 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Sensitisation Skin, category 1 H317 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic H400 environment Acute Hazard, Category 1 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40 E; R2 Xn; R21/22 Xn; R48/22 Xi; R36/38 R43 N; R50 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS01 GHS08 GHS07 GHS09
Signal word (CLP) :	-
Hazard statements (CLP) :	H203 - Explosive; fire, blast or projection hazard H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life
Precautionary statements (CLP) :	P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		HYDROXYLAMINE SULPHATE AR
CAS No. :		10039-54-0
EC Index No. :		612-123-00-2
EC No. :		233-118-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after skin contact :	Immediately call a POISON CENTER or doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). If skin irritation or rash occurs:
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes damage to organs. Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray.
Unsuitable extinguishing media :	dry chemical powder.
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard :	May form flammable/explosive vapour-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Explosive. Explosion risk in case of
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
No additional information available
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Hazardous waste due to potential risk of explosion.
Precautions for safe handling :	Do not subject to grinding/shock/…/friction. Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment.
Storage conditions :	Store in original container. Keep container tightly closed. Protect from moisture.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Colour
Colour :	White crystalline.
Odour :	odourless.
Odour threshold :	No data available
pH value :	3.6
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	170 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	1.9 g/cm3
Solubility :	Water: Freely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	Explosive; fire, blast or projection hazard.
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Explosive; fire, blast or projection hazard. Extreme risk of explosion by shock, friction, fire or
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Heat. Sparks. Open flame. Direct sunlight. Overheating.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Harmful in contact with skin. Oral: Harmful if swallowed.
Skin corrosion/irritation :	Causes skin irritation. pH: 3.6
Serious eye damage/irritation :	Causes serious eye irritation. pH: 3.6
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer.
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2865
UN-No. (IMDG) :	2865
UN-No. (IATA) :	2865
UN-No. (ADN) :	2865
UN-No. (RID) :	2865
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	HYDROXYLAMINE SULPHATE
Proper Shipping Name (IMDG) :	HYDROXYLAMINE SULPHATE
Proper Shipping Name (IATA) :	HYDROXYLAMINE SULPHATE
Proper Shipping Name (ADN) :	HYDROXYLAMINE SULPHATE
Proper Shipping Name (RID) :	HYDROXYLAMINE SULPHATE
Transport document description (ADR) :	UN 2865, HYDROXYLAMINE SULPHATE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2865, HYDROXYLAMINE SULPHATE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2865, HYDROXYLAMINE SULPHATE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2865, HYDROXYLAMINE SULPHATE, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2865, HYDROXYLAMINE SULPHATE, 8, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8
Danger labels :	8
IMDG
Transport hazard class(es) :	8
Danger labels :	8
IATA
Transport hazard class(es) :	8
Danger labels :	8
ADN
Transport hazard class(es) :	8
Danger labels :	8
RID
Transport hazard class(es) :	8
Danger labels :	8
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C2 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP7 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X
- Transport by sea
Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y845 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 860 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 864 CAO max net quantity (IATA) : 100kg ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C2 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C2 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV Transport category (RID) : 3 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions HYDROXYLAMINE SULPHATE AR is not on the REACH Candidate List HYDROXYLAMINE SULPHATE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 5092) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Carc. 2 Carcinogenicity, Category 2 Expl. 1.3 Explosives, Division 1.3 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation — Skin, category 1 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H203 Explosive; fire, blast or projection hazard H302 Harmful if swallowed H312 Harmful in contact with skin H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life R2 Risk of explosion by shock, friction, fire or other sources of ignition R21/22 Harmful in contact with skin and if swallowed R36/38 Irritating to eyes and skin R40 Limited evidence of a carcinogenic effect R43 May cause sensitisation by skin contact R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed R50 Very toxic to aquatic organisms E Explosive N Dangerous for the environment Xi Irritant Xn Harmful