n-PROPYLAMINE For Synthesis

n-PROPYLAMINE For Synthesis

Synonyms : 1-Aminopropane

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : n-PROPYLAMINE
Catalogue No. : AL3837 Product form : Substance
CAS Number : 107-10-8 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 29211990
Synonyms : 1-Aminopropane
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids,
Category 1
H224
Serious eye damage/eye
irritation, Category 2
H319
Skin corrosion/irritation,
Category 2
H315
Specific target organ
toxicity Single
exposure, Category 3,
H335
Respiratory tract irritation
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F+; R12
Xi; R36/37/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS07GHS07
Signal word (CLP) : -
Hazard statements (CLP) : H224 - Extremely flammable liquid and vapour
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Precautionary statements (CLP) : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : ISOPROPYLAMINE FOR SYNTHESIS
CAS No. : 107-10-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated
clothing. Wash with plenty of soap and water. Wash contaminated clothing before
reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see
... on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Extremely flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked
lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : No naked lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area.
Hygiene measures : Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting/… equipment.
Storage conditions : Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : ammonia like odour.
Odour threshold : No data available
pH value : 13 at 700 g/l at 20 °C
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -101 °C
Freezing point : No data available
Boiling point : 33 - 34
Flash point : -37 °C
Auto-ignition temperature : 402 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable Extremely flammable liquid and vapour
Vapour pressure : 634.1 hPa at 20 °C
Relative vapour density at 20°C : 2.04
Density : 0.6891 g/cm3
Solubility : Water: Soluble
Log Pow : -0.03
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.02 - 0.104 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Extremely flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Sparks. Heat. Direct sunlight. Overheating. Open flame.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes skin irritation.
pH: 13 at 700 g/l at 20 °C
Serious eye damage/irritation : Causes serious eye irritation.
pH: 13 at 700 g/l at 20 °C
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : ISOPROPYLAMINE FOR SYNTHESIS (75-31-0) Log Pow -0.03
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1221
UN-No. (IMDG) : 1221
UN-No. (IATA) : 1221
UN-No. (ADN) : 1221
UN-No. (RID) : 1221
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ISOPROPYLAMINE
Proper Shipping Name (IMDG) : ISOPROPYLAMINE
Proper Shipping Name (IATA) : ISOPROPYLAMINE
Proper Shipping Name (ADN) : ISOPROPYLAMINE
Proper Shipping Name (RID) : ISOPROPYLAMINE
Transport document description (ADR) : UN 1221, ISOPROPYLAMINE, 3 (8), I
Transport document description (IMDG) : UN 1221, ISOPROPYLAMINE, 3 (8), I
Transport document description (IATA) : UN 1221, ISOPROPYLAMINE, 3 (8), I
Transport document description (ADN) : UN 1221, ISOPROPYLAMINE, 3 (8), I
Transport document description (RID) : UN 1221, ISOPROPYLAMINE, 3 (8), I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
IMDG
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
IATA
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
ADN
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
RID
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FC
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P001
Mixed packing provisions (ADR) : MP7, MP17
Portable tank and bulk container
instructions (ADR)
: T11
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L10CH
Tank special provisions (ADR) : TU14, TE21
Vehicle for tank carriage : FL
Transport category (ADR) : 1
Special provisions for carriage - Operation
(ADR)
: S2, S20
Hazard identification number (Kemler No.) : 338
Orange plates :
Tunnel restriction code (ADR) : C/E
EAC code : •2WE
APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P001
Tank instructions (IMDG) : T11
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : E
Stowage and handling (IMDG) : SW2
Flash point (IMDG) : -37°C c.c.
MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : 350
PCA max net quantity (IATA) : 0.5L
CAO packing instructions (IATA) : 360
CAO max net quantity (IATA) : 2.5L
ERG code (IATA) : 3CH
- Inland waterway transport
Classification code (ADN) : FC
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : FC
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P001
Mixed packing provisions (RID) : MP7, MP17
Portable tank and bulk container
instructions (RID)
: T11
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L10CH
Special provisions for RID tanks (RID) : TU14, TU38, TE21, TE22
Transport category (RID) : 1
Hazard identification number (RID) : 338
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
ISOPROPYLAMINE FOR SYNTHESIS is not on the REACH Candidate List
ISOPROPYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to
VwVwS, Annex 3; WGK No 5981)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F+ ; Emergency management guidelines for the storage of flammable
liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Liq. 1 Flammable liquids, Category 1
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H224 Extremely flammable liquid and vapour
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
R12 Extremely flammable
R36/37/38 Irritating to eyes, respiratory system and skin
F+ Extremely flammable
Xi Irritant