SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	o-TOLIDINE HYDROCHLORIDE AR
Catalogue No. :	AL4589	Product form :	Substance
CAS Number :	612-82-8	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29214330
Synonyms :	3,3'-Dimethylbenzidine dihydrochloride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 4 H302 Carcinogenicity, Category 1A H350 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.1; R45 Xn; R22 N; R51/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H302 - Harmful if swallowed H350 - May cause cancer H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P273 - Avoid release to the environment P308+P313 - IF exposed or concerned: Get medical advice/attention
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		O-TOLIDINE HYDROCHLORIDE HYDRATE AR
CAS No. :		612-82-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : May cause cancer. Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not get in eyes, on skin, or on clothing.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	285.22 g/mol
Colour :	Off white crystalline.
Odour :	slight odor of hydrochloric acid.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	215 - 217
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	Water: Soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	May cause cancer.
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	O-TOLIDINE HYDROCHLORIDE HYDRATE AR (612-82-8) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3077
UN-No. (IMDG) :	3077
UN-No. (IATA) :	3077
UN-No. (ADN) :	3077
UN-No. (RID) :	3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (ADN) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	9
Danger labels :	9
IMDG
Transport hazard class(es) :	9
Danger labels :	9
IATA
Transport hazard class(es) :	9
Danger labels :	9
ADN
Transport hazard class(es) :	9
Danger labels :	9
RID
Transport hazard class(es) :	9
Danger labels :	9
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M7 Special provision (ADR) : 274, 335, 601, 375 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : PP12, B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1, BK1, BK2 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV, LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V13 Special provisions for carriage - Bulk (ADR) : VC1, VC2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z
- Transport by sea
Special provision (IMDG) : 274, 335, 966, 967, 969 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 Packing provisions (IMDG) : PP12 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1, BK1, BK2, BK3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F Stowage category (IMDG) : A Stowage and handling (IMDG) : SW23 MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y956 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 956 PCA max net quantity (IATA) : 400kg CAO packing instructions (IATA) : 956 CAO max net quantity (IATA) : 400kg Special provision (IATA) : A97, A158, A179, A197 ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M7 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T* B** Equipment required (ADN) : PP, A Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : M7 Special provision (RID) : 274, 335, 375, 601 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : PP12, B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1, BK1, BK2 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV, LGBV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W13 Special provisions for carriage – Bulk (RID) : VC1, VC2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW31 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions O-TOLIDINE HYDROCHLORIDE HYDRATE AR is not on the REACH Candidate List O-TOLIDINE HYDROCHLORIDE HYDRATE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Carc. 1A Carcinogenicity, Category 1A H302 Harmful if swallowed H350 May cause cancer H411 Toxic to aquatic life with long lasting effects R22 Harmful if swallowed R45 May cause cancer R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xn Harmful