2-(ETHYLAMINO) ETHANOL For Synthesis

2-(ETHYLAMINO) ETHANOL For Synthesis

Synonyms : N-Ethylethanolamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : 2-(ETHYLAMINO) ETHANOL (for synthesis)
Catalogue No. : AL2046 Product form : Substance
CAS Number : 110-73-6 EC Number :
Grade : EC Index Number :
Chemical Formula : C4H11NO HSN Code : 29221990
Synonyms : N-Ethylethanolamine
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal),
Category 3
H311
Serious eye damage/eye
irritation, Category 1
H318
Acute toxicity (oral),
Category 4
H302
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R24
Xn; R22
Xi; R41
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS05GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H302 - Harmful if swallowed.
H311 - Toxic in contact with skin.
H318 - Causes serious eye damage.
Precautionary statements (CLP) : P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER/doctor if you feel unwell.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 2-(ETHYLAMINO) ETHANOL FOR SYNTHESIS
CAS No. : 110-73-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Wash with plenty of water/…. Wash
contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after skin contact : Toxic in contact with skin.
Symptoms/effects after eye contact : Causes serious eye damage.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 89.14 g/mol
Colour : Clear Colorless.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -90 °C
Freezing point : No data available
Boiling point : 165 °C
Flash point : 71 °C
Auto-ignition temperature : 330 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : < 1 mm Hg 20 °C
Relative vapour density at 20°C : 3
Density : 0.914 g/cm3
Solubility : Water: Miscible in cold water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.011 - 0.117 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Toxic in contact with skin. Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed. Toxic in contact with skin

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2810
UN-No. (IMDG) : 2810
UN-No. (IATA) : 2810
UN-No. (ADN) : 2810
UN-No. (RID) : 2810
14.2. UN proper shipping name
Proper Shipping Name (ADR) : TOXIC LIQUID, ORGANIC, N.O.S.
Proper Shipping Name (IMDG) : TOXIC LIQUID, ORGANIC, N.O.S.
Proper Shipping Name (IATA) : TOXIC LIQUID, ORGANIC, N.O.S.
Proper Shipping Name (ADN) : TOXIC LIQUID, ORGANIC, N.O.S.
Proper Shipping Name (RID) : TOXIC LIQUID, ORGANIC, N.O.S.
Transport document description (ADR) : UN 2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III
Transport document description (IMDG) : UN 2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III
Transport document description (IATA) : UN 2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III
Transport document description (ADN) : UN 2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III
Transport document description (RID) : UN 2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T1
Special provisions (ADR) : 274, 614
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP1, TP28
Tank code (ADR) : L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V12
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
APP code : B
- Transport by sea
Special provisions (IMDG) : 223, 274
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1, TP28
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW2
Properties and observations (IMDG) : Toxic if swallowed, by skin contact or by inhalation.
MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y642
PCA limited quantity max net quantity
(IATA)
: 2L
PCA packing instructions (IATA) : 655
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 663
CAO max net quantity (IATA) : 220L
Special provisions (IATA) : A3, A4, A137
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T1
Special provisions (ADN) : 274, 614, 802
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, TOX, A
Ventilation (ADN) : VE02
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T1
Special provisions (RID) : 274, 614
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP1, TP28
Tank codes for RID tanks (RID) : L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W12
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
2-(ETHYLAMINO) ETHANOL FOR SYNTHESIS is not on the REACH Candidate List
2-(ETHYLAMINO) ETHANOL FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 1610)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H318 Causes serious eye damage.
R22 Harmful if swallowed
R24 Toxic in contact with skin
R41 Risk of serious damage to eyes
T Toxic
Xi Irritant
Xn Harmful