SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	TRIETHYLENE TETRAMINE
Catalogue No. :	AL4657	Product form :	Substance
CAS Number :	112-24-3	EC Number :	203-950-6
Grade :		EC Index Number :	612-059-00-5
Chemical Formula :		HSN Code :	29212990
Synonyms :	DEH 24, EPH 925
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal), Category 4 H312 Skin corrosion/irritation, Category 1B H314 Skin sensitisation, Category 1 H317 Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R21 C; R34 R43 R52/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS07
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H312 - Harmful in contact with skin. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a doctor.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		TRIETHYLENE TETRAMINE for Synthesis
CAS No. :		112-24-3
EC Index No. :		612-059-00-5
EC No. :		203-950-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : May cause an allergic skin reaction. Symptoms/effects after skin contact : Harmful in contact with skin. Symptoms/effects after eye contact : Causes serious eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe vapours. Avoid contact with skin and eyes. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Contaminated work clothing should not be allowed out of the workplace.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	146.24 g/mol
Colour :	light yellow.
Odour :	ammonia like.
Odour threshold :	No data available
pH value :	10
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-37.2 °C
Freezing point :	No data available
Boiling point :	272 °C
Flash point :	113 °C
Auto-ignition temperature :	337.8 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	< 0.01 mm Hg @ 20°C
Relative vapour density at 20°C :	5
Density :	0.98 g/cm3
Solubility :	Water: Soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Harmful in contact with skin.
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 10
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 10
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	TRIETHYLENE TETRAMINE for Synthesis (112-24-3) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2259
UN-No. (IMDG) :	2259
UN-No. (IATA) :	2259
UN-No. (ADN) :	2259
UN-No. (RID) :	2259
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	TRIETHYLENETETRAMINE
Proper Shipping Name (IMDG) :	TRIETHYLENETETRAMINE
Proper Shipping Name (IATA) :	TRIETHYLENETETRAMINE
Proper Shipping Name (ADN) :	TRIETHYLENETETRAMINE
Proper Shipping Name (RID) :	TRIETHYLENETETRAMINE
Transport document description (ADR) :	UN 2259, TRIETHYLENETETRAMINE, 8, II
Transport document description (IMDG) :	UN 2259, TRIETHYLENETETRAMINE, 8, II
Transport document description (IATA) :	UN 2259, TRIETHYLENETETRAMINE, 8, II
Transport document description (ADN) :	UN 2259, TRIETHYLENETETRAMINE, 8, II
Transport document description (RID) :	UN 2259, TRIETHYLENETETRAMINE, 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8
Danger labels :	8
IMDG
Transport hazard class(es) :	8
Danger labels :	8
IATA
Transport hazard class(es) :	8
Danger labels :	8
ADN
Transport hazard class(es) :	8
Danger labels :	8
RID
Transport hazard class(es) :	8
Danger labels :	8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C7 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : B Stowage and handling (IMDG) : SW2 Segregation (IMDG) : SG35 MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C7 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C7 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions TRIETHYLENE TETRAMINE for Synthesis is not on the REACH Candidate List TRIETHYLENE TETRAMINE for Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 1297) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1 Skin sensitisation, Category 1 H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. R21 Harmful in contact with skin R34 Causes burns R43 May cause sensitisation by skin contact R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment C Corrosive Xn Harmful