tert-BUTYLAMINE For Synthesis |
Synonyms : 2-Amine-2-methylpropane |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | tert-BUTYLAMINE | ||
Catalogue No. : | AL0962 | Product form : | Substance |
CAS Number : | 75-64-9 | EC Number : | |
Grade : | EC Index Number : | ||
Chemical Formula : | HSN Code : | 29211190 | |
Synonyms : | 2-Amino-2-methylpropane | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Industrial For professional use only | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Flammable liquids, Category 2 H225 Skin corrosion/irritation, Category 1A H314 Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Full text of H statements : see section 16 |
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Classification according to Directive 67/548/EEC or 1999/45/EC | |
F; C; T; R11-20/22-35 Full text of R-phrases: see section 16 |
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Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS02 GHS05 GHS07 |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H225 - Highly flammable liquid and vapour. H302+H332 - Harmful if swallowed or if inhaled H314 - Causes severe skin burns and eye damage. |
Precautionary statements (CLP) : | P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Name : | tert-BUTYLAMINE FOR SYNTHESIS | ||
CAS No. : | 75-64-9 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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Not applicable |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. |
First-aid measures after skin contact : | Rinse skin with water/shower. Take off immediately all contaminated clothing. Immediately call a POISON CENTER/doctor. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : Harmful if inhaled. Symptoms/effects after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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Fire hazard : | Highly flammable liquid and vapour. |
Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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Emergency procedures : | Avoid contact with skin, eyes and clothing. |
6.1.2. For emergency responders |
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Protective equipment | Use personal protective equipment as required |
Emergency procedures | Stop release. |
6.2 Environmental precautions |
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Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | Clean up immediately by sweeping or vacuum. |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
Precautions for safe handling : | No open flames. No smoking. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. |
Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Comply with applicable regulations. |
Storage conditions : | Keep in fireproof place. Keep container tightly closed. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | Protective gloves |
Eye protection : | Chemical goggles or face shield |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Liquid |
Molecular mass : | 73.14 g/mol |
Colour : | Clear Colorless. |
Odour : | ammonia odor. |
Odour threshold : | No data available |
pH value : | 12.1 at 100 g/l at 25 °C |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | -67 °C |
Freezing point : | No data available |
Boiling point : | 46 °C |
Flash point : | -38 °C |
Auto-ignition temperature : | 380 °C |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | Extremely Flammable Highly flammable liquid and v |
Vapour pressure : | 392.9 hPa at 20 °C |
Relative vapour density at 20°C : | 2.53 |
Density : | 0.696 g/cm3 |
Solubility : | Water: Completely soluble |
Log Pow : | 0.4 |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | 0.017 - 0.098 vol % |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture. | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Open flame. Direct sunlight. | |
10.5 Incompatible materials |
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No additional information available | |
10.6 Hazardous decomposition products |
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May release flammable gases. Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Inhalation: Harmful if inhaled. Oral: Harmful if swallowed. |
Skin corrosion/irritation : | Causes severe skin burns and eye damage. pH: 12.1 at 100 g/l at 25 °C |
Serious eye damage/irritation : | Serious eye damage, category 1, implicit pH: 12.1 at 100 g/l at 25 °C |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Not classified |
STOT-single exposure : | Not classified |
STOT-repeated exposure : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | tert-BUTYLAMINE FOR SYNTHESIS (75-64-9) Log Pow 0.4 |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 2734 |
UN-No. (IMDG) : | 2734 |
UN-No. (IATA) : | 2734 |
UN-No. (ADN) : | 2734 |
UN-No. (RID) : | 2734 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
Proper Shipping Name (IMDG) : | AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
Proper Shipping Name (IATA) : | AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
Proper Shipping Name (ADN) : | AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
Proper Shipping Name (RID) : | AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
Transport document description (ADR) : | UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I |
Transport document description (IMDG) : | UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I |
Transport document description (IATA) : | UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I |
Transport document description (ADN) : | UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I |
Transport document description (RID) : | UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 8 (3) |
Danger labels : | 8, 3 |
IMDG | |
Transport hazard class(es) : | 8 (3) |
Danger labels : | 8, 3 |
IATA | |
Transport hazard class(es) : | 8 (3) |
Danger labels : | 8, 3 |
ADN | |
Transport hazard class(es) : | 8 (3) |
Danger labels : | 8, 3 |
RID | |
Transport hazard class(es) : | 8 (3) |
Danger labels : | 8, 3 |
14.4. Packing group |
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Packing group (ADR) : | I |
Packing group (IMDG) : | I |
Packing group (IATA) : | I |
Packing group (ADN) : | I |
Packing group (RID) : | I |
14.5. Environmental hazards |
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Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : CF1 Special provisions (ADR) : 274 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001 Mixed packing provisions (ADR) : MP8, MP17 Portable tank and bulk container instructions (ADR) : T14 Portable tank and bulk container special provisions (ADR) : TP2, TP27 Tank code (ADR) : L10BH Vehicle for tank carriage : FL Transport category (ADR) : 1 Special provisions for carriage - Operation (ADR) : S2, S14 Hazard identification number (Kemler No.) : 883 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2W APP code : A(fl) |
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- Transport by sea | |
Special provisions (IMDG) : 274 Packing instructions (IMDG) : P001 Tank instructions (IMDG) : T14 Tank special provisions (IMDG) : TP2, TP27 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : A Segregation (IMDG) : SG35 Properties and observations (IMDG) : Colourless to yellowish flammable liquids or solutions with a pungent odour. Miscible with water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. Reacts violently with acids. Cause burns to skin, eyes and mucous membranes. MFAG-No : 132 |
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- Air transport | |
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : 850 PCA max net quantity (IATA) : 0.5L CAO packing instructions (IATA) : 854 CAO max net quantity (IATA) : 2.5L ERG code (IATA) : 8F |
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- Inland waterway transport | |
Classification code (ADN) : CF1 Special provisions (ADN) : 274 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1 |
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- Rail transport | |
Classification code (RID) : CF1 Special provisions (RID) : 274 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P001 Mixed packing provisions (RID) : MP8, MP17 Portable tank and bulk container instructions (RID) : T14 Portable tank and bulk container special provisions (RID) : TP2, TP27 Tank codes for RID tanks (RID) : L10BH Special provisions for RID tanks (RID) : TU38, TE22 Transport category (RID) : 1 Hazard identification number (RID) : 883 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions tert-BUTYLAMINE FOR SYNTHESIS is not on the REACH Candidate List tert-BUTYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 1510) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Netherlands |
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
Denmark |
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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