p-TOLUIDINE AR |
| Synonyms : 4-Aminotoluene, 4-Methylaniline |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | p-TOLUIDINE AR | ||
| Catalogue No. : | AL4619 | Product form : | Substance |
| CAS Number : | 106-49-0 | EC Number : | 203-403-1 |
| Grade : | EC Index Number : | 612-160-00-4 | |
| Chemical Formula : | HSN Code : | 29214350 | |
| Synonyms : | 4-Aminotoluene, 4-Methylaniline | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Carcinogenicity, Category 2 H351 Serious eye damage/eye irritation, Category 2 H319 Sensitisation Skin, category 1 H317 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 T; R23/24/25 Xi; R36 R43 N; R50 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
 GHS09
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| Signal word (CLP) : | - |
| Hazard statements (CLP) : | H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H351 - Suspected of causing cancer H400 - Very toxic to aquatic life |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a POISON CENTER or doctor/physician |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | p-TOLUIDINE AR | ||
| CAS No. : | 106-49-0 | ||
| EC Index No. : | 612-160-00-4 | ||
| EC No. : | 203-403-1 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries after inhalation : May cause an allergic skin reaction. Toxic if inhaled. Symptoms/injuries after skin contact : Toxic in contact with skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Very toxic to aquatic life. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Do not get in eyes, on skin, or on clothing. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 107.16 g/mol |
| Colour : | White crystalline. |
| Odour : | aromatic odor. |
| Odour threshold : | No data available |
| pH value : | 7.8 |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 42 - 45 |
| Freezing point : | No data available |
| Boiling point : | 200 °C |
| Flash point : | 87 °C |
| Auto-ignition temperature : | 482 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 1 mm Hg at 20C |
| Relative vapour density at 20°C : | 3.9 |
| Density : | 0.973 g/cm3 |
| Solubility : | Water: Insoluble in water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Overheating. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. |
| Skin corrosion/irritation : | Not classified pH: 7.8 |
| Serious eye damage/irritation : | Causes serious eye irritation. pH: 7.8 |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life. |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 3451 |
| UN-No. (IMDG) : | 3451 |
| UN-No. (IATA) : | 3451 |
| UN-No. (ADN) : | 3451 |
| UN-No. (RID) : | 3451 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | TOLUIDINES, SOLID |
| Proper Shipping Name (IMDG) : | TOLUIDINES, SOLID |
| Proper Shipping Name (IATA) : | TOLUIDINES, SOLID |
| Proper Shipping Name (ADN) : | TOLUIDINES, SOLID |
| Proper Shipping Name (RID) : | TOLUIDINES, SOLID |
| Transport document description (ADR) : | UN 3451, TOLUIDINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 3451, TOLUIDINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 3451, TOLUIDINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 3451, TOLUIDINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 3451, TOLUIDINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T2 Special provision (ADR) : 279 Limited quantities (ADR) : 500g Excepted quantities (ADR) : E4 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X |
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| - Transport by sea | |
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Special provision (IMDG) : 279 Limited quantities (IMDG) : 500 g Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B2, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A MFAG-No : 153 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y644 PCA limited quantity max net quantity (IATA) : 1kg PCA packing instructions (IATA) : 669 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 676 CAO max net quantity (IATA) : 100kg Special provision (IATA) : A113 ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T2 Special provisions (ADN) : 279, 802 Limited quantities (ADN) : 500 g Excepted quantities (ADN) : E4 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 2 |
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| - Rail transport | |
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Classification code (RID) : T2 Special provision (RID) : 279 Limited quantities (RID) : 500g Excepted quantities (RID) : E4 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE9 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions p-TOLUIDINE AR is not on the REACH Candidate List p-TOLUIDINE AR is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK No 693) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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