MERCURIC OXIDE YELLOW AR

MERCURIC OXIDE YELLOW AR

Synonyms : Mercury(II) oxide yellow

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : MERCURIC OXIDE YELLOW AR
Catalogue No. : AL2951 Product form : Substance
CAS Number : 21908-53-2 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28521000
Synonyms : Mercury(II) oxide yellow
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal),
Category 1
H310
Acute toxicity (inhal.),
Category 2
H330
Acute toxicity (oral),
Category 1
H300
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T+; R26/27/28
N; R50/53
R33
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS09GHS09 GHS08GHS08
Signal word (CLP) : Danger
Hazard statements (CLP) : H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P264 - Wash ... thoroughly after handling
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : MERCURIC OXIDE YELLOW AR
CAS No. : 21908-53-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Immediately call a POISON CENTER or doctor/physician. Specific measures (see ...
on this label). Gently wash with plenty of soap and water. Remove/Take off
immediately all contaminated clothing. Wash contaminated clothing before reuse.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Specific
treatment (see ... on this label).
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : There are potential chronic health effects to consider.
Symptoms/injuries after skin contact : Fatal in contact with skin.
Symptoms/injuries after ingestion : Fatal if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media :
Unsuitable extinguishing media :
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : No additional information available

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing.
Hygiene measures : Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : Orange red to yellow.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : 0.6
Melting point : 500 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 11.14 g/cm3
Solubility : Water: Insoluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Fatal in contact with skin. Inhalation: Fatal if inhaled. Oral: Fatal if
swallowed.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified Additional information
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Fatal if swallowed. Fatal in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : MERCURIC OXIDE YELLOW AR (21908-53-2) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1641
UN-No. (IMDG) : 1641
UN-No. (IATA) : 1641
UN-No. (ADN) : 1641
UN-No. (RID) : 1641
14.2. UN proper shipping name
Proper Shipping Name (ADR) : MERCURY OXIDE
Proper Shipping Name (IMDG) : MERCURY OXIDE
Proper Shipping Name (IATA) : MERCURY OXIDE
Proper Shipping Name (ADN) : MERCURY OXIDE
Proper Shipping Name (RID) : MERCURY OXIDE
Transport document description (ADR) : UN 1641, MERCURY OXIDE, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 1641, MERCURY OXIDE, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 1641, MERCURY OXIDE, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1641, MERCURY OXIDE, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1641, MERCURY OXIDE, 6.1, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T5
Limited quantities (ADR) : 500g
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9, S19
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : 2X
- Transport by sea
Limited quantities (IMDG) : 500 g
Excepted quantities (IMDG) : E4
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
MFAG-No : 151
- Air transport
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y644
PCA limited quantity max net quantity
(IATA)
: 1kg
PCA packing instructions (IATA) : 669
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 676
CAO max net quantity (IATA) : 100kg
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T5
Special provisions (ADN) : 802
Limited quantities (ADN) : 500 g
Excepted quantities (ADN) : E4
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : T5
Limited quantities (RID) : 500g
Excepted quantities (RID) : E4
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W11
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE9
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
MERCURIC OXIDE YELLOW AR is not on the REACH Candidate List
MERCURIC OXIDE YELLOW AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to VwVwS, Annex 2; WGK No 408)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1
Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
H300 Fatal if swallowed
H310 Fatal in contact with skin
H330 Fatal if inhaled
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
N Dangerous for the environment
T+ Very toxic