SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	AMMONIUM SULPHIDE YELLOW (solution)
Catalogue No. :	AL0401	Product form :	Substance
CAS Number :	12135-76-1	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	28309010
Synonyms :	Ammonium hydrosulfide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Skin corrosion/irritation, Category 1B H314 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R34 R10 R31 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour H314 - Causes severe skin burns and eye damage H400 - Very toxic to aquatic life
Precautionary statements (CLP) :	P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		AMMONIUM SULPHIDE SOLUTION IN WATER EXTRA PURE
CAS No. :		12135-76-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact :	Wash with plenty of water/….
First-aid measures after eye contact :	Rinse immediately with plenty of water.
First-aid measures after ingestion :	Rinse mouth.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Wash ... thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment. Comply with applicable regulations.
Storage conditions :	Keep container tightly closed. Store in original container. Store in a dry place. Store in a well-ventilated place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	68.14 g/mol
Colour :	Clear Yellow.
Odour :	ammonia odour.
Odour threshold :	No data available
pH value :	9.5 (45% aqueous solution)
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	32.2 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour
Vapour pressure :	600 hPa at 20 °C
Relative vapour density at 20°C :	No data available
Density :	0.997 g/cm3
Solubility :	Water: Infinitely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.04 - 0.46 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
Highly reactive material. Contact with acids liberates toxic gas.
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 9.5 (45% aqueous solution)
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 9.5 (45% aqueous solution)
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2683
UN-No. (IMDG) :	2683
UN-No. (IATA) :	2683
UN-No. (ADN) :	2683
UN-No. (RID) :	2683
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	AMMONIUM SULPHIDE SOLUTION
Proper Shipping Name (IMDG) :	AMMONIUM SULPHIDE SOLUTION
Proper Shipping Name (IATA) :	AMMONIUM SULPHIDE SOLUTION
Proper Shipping Name (ADN) :	AMMONIUM SULPHIDE SOLUTION
Proper Shipping Name (RID) :	AMMONIUM SULPHIDE SOLUTION
Transport document description (ADR) :	UN 2683, AMMONIUM SULPHIDE SOLUTION, 8 (3, 6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2683, AMMONIUM SULPHIDE SOLUTION, 8 (3, 6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2683, AMMONIUM SULPHIDE SOLUTION, 8 (3, 6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2683, AMMONIUM SULPHIDE SOLUTION, 8 (3, 6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2683, AMMONIUM SULPHIDE SOLUTION, 8 (3, 6.1), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (3, 6.1)
Danger labels :	8, 3, 6.1
IMDG
Transport hazard class(es) :	8 (3, 6.1)
Danger labels :	8, 3, 6.1
IATA
Transport hazard class(es) :	8 (3, 6.1)
Danger labels :	8, 3, 6.1
ADN
Transport hazard class(es) :	8 (3, 6.1)
Danger labels :	8, 3, 6.1
RID
Transport hazard class(es) :	8 (3, 6.1)
Danger labels :	8, 3, 6.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CFT Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC01 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 86 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2W APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC01 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : B Stowage and handling (IMDG) : SW1, H2 Segregation (IMDG) : SG35, SG68 MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8FP
- Inland waterway transport
Classification code (ADN) : CFT Special provisions (ADN) : 802 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : CFT Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC01 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 86
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions AMMONIUM SULPHIDE SOLUTION IN WATER EXTRA PURE is not on the REACH Candidate List AMMONIUM SULPHIDE SOLUTION IN WATER EXTRA PURE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 297) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1B Skin corrosion/irritation, Category 1B H226 Flammable liquid and vapour H314 Causes severe skin burns and eye damage H400 Very toxic to aquatic life R10 Flammable R31 Contact with acids liberates toxic gas R34 Causes burns C Corrosive