AMMONIUM METAVANADATE Extra Pure

AMMONIUM METAVANADATE Extra Pure

Synonyms : Ammonium vanadate(V)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : AMMONIUM METAVANADATE (ammonium monovanadate)
Catalogue No. : AL0366 Product form : Substance
CAS Number : 7803-55-6 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28419000
Synonyms : Ammonium vanadate(V)
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral),
Category 3
H301
Acute toxicity (inhal.),
Category 1
H330
Skin corrosion/irritation,
Category 2
H315
Serious eye damage/eye
irritation, Category 2
H319
Specific target organ
toxicity Single
exposure, Category 3,
Respiratory tract irritation
H335
Full text of hazard classes and H-statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R25
Xn; R20
Xi; R36
Xi; R37
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06
Signal word (CLP) : Danger
Hazard statements (CLP) : H301 - Toxic if swallowed.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H330 - Fatal if inhaled.
H335 - May cause respiratory irritation.
Precautionary statements (CLP) : P260 - Do not breathe vapours, dust, fume, gas.
P284 - [In case of inadequate ventilation] wear respiratory protection.
P301+P310 - IF SWALLOWED: Immediately call a doctor.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a doctor.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : AMMONIUM METAVANADATE Extra Pure
CAS No. : 7803-55-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated clothing before reuse. Get
medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : White or yellowish-white.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 200 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : Water: Slight (0.1-1%)
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed. Inhalation: Fatal if inhaled.
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2859
UN-No. (IMDG) : 2859
UN-No. (IATA) : 2859
UN-No. (ADN) : 2859
UN-No. (RID) : 2859
14.2. UN proper shipping name
Proper Shipping Name (ADR) : AMMONIUM METAVANADATE
Proper Shipping Name (IMDG) : AMMONIUM METAVANADATE
Proper Shipping Name (IATA) : AMMONIUM METAVANADATE
Proper Shipping Name (ADN) : AMMONIUM METAVANADATE
Proper Shipping Name (RID) : AMMONIUM METAVANADATE
Transport document description (ADR) : UN 2859, AMMONIUM METAVANADATE, 6.1, II
Transport document description (IMDG) : UN 2859, AMMONIUM METAVANADATE, 6.1, II
Transport document description (IATA) : UN 2859, AMMONIUM METAVANADATE, 6.1, II
Transport document description (ADN) : UN 2859, AMMONIUM METAVANADATE, 6.1, II
Transport document description (RID) : UN 2859, AMMONIUM METAVANADATE, 6.1, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T5
Limited quantities (ADR) : 500g
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9, S19
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : 2Z
- Transport by sea
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B21, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
Segregation (IMDG) : SG6, SG8, SG10, SG12
Properties and observations (IMDG) : White crystalline powder. Slightly soluble in water. May act as an oxidizing
substance. Toxic if swallowed, by skin contact or by inhalation.
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y644
PCA limited quantity max net quantity
(IATA)
: 1kg
PCA packing instructions (IATA) : 669
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 676
CAO max net quantity (IATA) : 100kg
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T5
Special provisions (ADN) : 802
Limited quantities (ADN) : 500 g
Excepted quantities (ADN) : E4
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : T5
Excepted quantities (RID) : E4
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W11
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE9
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
AMMONIUM METAVANADATE Extra Pure is not on the REACH Candidate List
AMMONIUM METAVANADATE Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 1 (Inhalation) Acute toxicity (inhal.), Category 1
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H301 Toxic if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
R20 Harmful by inhalation
R25 Toxic if swallowed