BROMOBENZENE Extra Pure |
Synonyms : Phenylbromide; Monobromobenzene |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | BROMOBENZENE (for synthesis) (phenyl bromide) | ||
Catalogue No. : | AL0830 | Product form : | Substance |
CAS Number : | 108-86-1 | EC Number : | 203-623-8 |
Grade : | EC Index Number : | 602-060-00-9 | |
Chemical Formula : | HSN Code : | 29039990 | |
Synonyms : | Phenylbromide; Monobromobenzene | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Flammable liquids, Category 3 H226 Skin corrosion/irritation, Category 2 H315 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16 |
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Classification according to Directive 67/548/EEC or 1999/45/EC | |
Xi; R38 N; R51/53 R10 Full text of R-phrases: see section 16 |
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Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS02 GHS07 GHS09 |
Signal word (CLP) : | Warning |
Hazard statements (CLP) : | H226 - Flammable liquid and vapour H315 - Causes skin irritation H411 - Toxic to aquatic life with long lasting effects |
Precautionary statements (CLP) : | P273 - Avoid release to the environment |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Name : | BROMOBENZENE Extra Pure | ||
CAS No. : | 108-86-1 | ||
EC Index No. : | 602-060-00-9 | ||
EC No. : | 203-623-8 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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Not applicable |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
First-aid measures after skin contact : | Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. |
First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/injuries after skin contact : Causes skin irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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Fire hazard : | Flammable liquid and vapour. |
Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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General measures : | Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. |
6.1.1. For non-emergency personnel |
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Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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Protective equipment | Use personal protective equipment as required |
Emergency procedures | Stop release. |
6.2 Environmental precautions |
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Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
Precautions for safe handling : | No naked lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. |
Hygiene measures : | Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment. |
Storage conditions : | Keep container tightly closed. Store in original container. Store in a dry place. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | protective gloves |
Eye protection : | Chemical goggles or safety glasses |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear appropriate mask |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Liquid |
Molecular mass : | 157.02 g/mol |
Colour : | Clear Colorless. |
Odour : | characteristic aromatic odor. |
Odour threshold : | No data available |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | -31 °C |
Freezing point : | No data available |
Boiling point : | 154 - 155 |
Flash point : | 51 °C |
Auto-ignition temperature : | 566 °C |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | Flammable Flammable liquid and vapour |
Vapour pressure : | 5.3 hPa at 25,0 °C |
Relative vapour density at 20°C : | 5.41 |
Density : | 1.5 g/cm3 |
Solubility : | Water: Insoluble |
Log Pow : | 2.99 |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | 0.06 - 0.365 vol % |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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No additional information available | |
10.2 Chemical stability |
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Flammable liquid and vapour. May form flammable/explosive vapour-air mixture. | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Open flame. Overheating. Direct sunlight. Heat. Sparks. | |
10.5 Incompatible materials |
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No additional information available | |
10.6 Hazardous decomposition products |
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May release flammable gases. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Not classified |
Skin corrosion/irritation : | Causes skin irritation. |
Serious eye damage/irritation : | Not classified |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Not classified |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | Not classified |
Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | Ecology - water : Toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
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Persistence - degradability : | BROMOBENZENE Extra Pure (108-86-1) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | BROMOBENZENE Extra Pure (108-86-1) Log Pow 2.99 |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 2514 |
UN-No. (IMDG) : | 2514 |
UN-No. (IATA) : | 2514 |
UN-No. (ADN) : | 2514 |
UN-No. (RID) : | 2514 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | BROMOBENZENE |
Proper Shipping Name (IMDG) : | BROMOBENZENE |
Proper Shipping Name (IATA) : | BROMOBENZENE |
Proper Shipping Name (ADN) : | BROMOBENZENE |
Proper Shipping Name (RID) : | BROMOBENZENE |
Transport document description (ADR) : | UN 2514, BROMOBENZENE, 3, III ENVIRONMENTALLY HAZARDOUS |
Transport document description (IMDG) : | UN 2514, BROMOBENZENE, 3, III ENVIRONMENTALLY HAZARDOUS |
Transport document description (IATA) : | UN 2514, BROMOBENZENE, 3, III ENVIRONMENTALLY HAZARDOUS |
Transport document description (ADN) : | UN 2514, BROMOBENZENE, 3, III ENVIRONMENTALLY HAZARDOUS |
Transport document description (RID) : | UN 2514, BROMOBENZENE, 3, III ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 3 |
Danger labels : | 3 |
IMDG | |
Transport hazard class(es) : | 3 |
Danger labels : | 3 |
IATA | |
Transport hazard class(es) : | 3 |
Danger labels : | 3 |
ADN | |
Transport hazard class(es) : | 3 |
Danger labels : | 3 |
RID | |
Transport hazard class(es) : | 3 |
Danger labels : | 3 |
14.4. Packing group |
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Packing group (ADR) : | III |
Packing group (IMDG) : | III |
Packing group (IATA) : | III |
Packing group (ADN) : | III |
Packing group (RID) : | III |
14.5. Environmental hazards |
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Dangerous for the environment : | Yes |
Marine pollutant : | Yes |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : F1 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T2 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2Y |
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- Transport by sea | |
Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Flash point (IMDG) : 51°C c.c. MFAG-No : 130 |
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- Air transport | |
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y344 PCA limited quantity max net quantity (IATA) : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L ERG code (IATA) : 3L |
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- Inland waterway transport | |
Classification code (ADN) : F1 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 0 |
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- Rail transport | |
Classification code (RID) : F1 Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T2 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Colis express (express parcels) (RID) : CE4 Hazard identification number (RID) : 30 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions BROMOBENZENE Extra Pure is not on the REACH Candidate List BROMOBENZENE Extra Pure is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 flammable liquids must be followed |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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